2-异氰基-1,3,5-三甲基苯合成路线 （共 9 条）
反应条件
potassium iodide in dimethyl sulfoxide 4 h;
参考文献
Russell, Glen A.; Rajaratnam, Ragine; Chen, Ping
Acta Chemica Scandinavica, 1998 , vol. 52, # 5 p. 528 - 532
反应条件
in benzene Irradiation;
参考文献
Russell, Glen A.; Rajaratnam, Ragine; Chen, Ping
Acta Chemica Scandinavica, 1998 , vol. 52, # 5 p. 528 - 532
反应条件
T=520 - 550°C; P=0.01 Torr;
参考文献
Meier, Michael; Ruechardt, Christoph
Chemische Berichte, 1987 , vol. 120, p. 1 - 4
反应条件
1: With trichlorophosphate in dichloromethane
T=-60°C; 0.416667 h;
2: With triethylamine in dichloromethane
T=-60 - 20°C;
参考文献
BASF SE; BASF (CHINA) COMPANY LIMITED; HASHMI, A., Stephen K.; LOTHSCHUeTZ, Christian
Patent: WO2012/56419 A1, 2012 ;
Location in patent: Page/Page column 63 ;
反应条件
1: 2,4,6-trimethylbenzenamine With 15-crown-5; sodium hydride in benzene
T=40 - 50°C; 0.25 h;
2: chloroform in benzene
T=40°C; 1 h;
参考文献
Bardsley, Kathryn; Hagigeorgiou, Michael; Lengyel, Istvan; Cesare, Victor
Synthetic Communications, 2013 , vol. 43, # 12 p. 1727 - 1733
反应条件
1.1: 12 h / 200 °C / Autoclave
2.1: trichlorophosphate / dichloromethane / 0.42 h / -60 °C
2.2: -60 - 20 °C
View Scheme
参考文献
Hashmi, A. Stephen K.; Lothschuetz, Christian; Boehling, Constantin; Hengst, Tobias; Hubbert, Christoph; Rominger, Frank
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 17 p. 3001 - 3012
反应条件
in chloroform-d1
T=60°C; ΔH(excit.), ΔS(excit.); Rate constantKineticsThermodynamic data;
参考文献
Minoura, Mao; Kawashima, Takayuki; Okazaki, Renji
Chemistry Letters, 1994 , # 9 p. 1691 - 1692
参考文献
Gruetzmacher, Hansjoerg; Freitag, Stefanie; Herbst-Irmer, Regine; Sheldrick, George M.
Angewandte Chemie, 1992 , vol. 104, p. 459 - 461
参考文献
Gruetzmacher, Hansjoerg; Freitag, Stefanie; Herbst-Irmer, Regine; Sheldrick, George M.
Angewandte Chemie, 1992 , vol. 104, p. 459 - 461
