1,3,3-三甲基-2-硫杂双环[2.2.2]辛烷合成路线 （共 6 条）
参考文献
Weitkamp
Journal of the American Chemical Society, 1959 , vol. 81, p. 3430,3431
参考文献
Weitkamp
Journal of the American Chemical Society, 1959 , vol. 81, p. 3430,3431
反应条件
bis(acetylacetonate)nickel(II); SCl2; diisobutylaluminium hydride
1) hexane, 5 deg C, 20 h, 2) toluene, r.t., 2 h; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Tolstikov, G. A.; Lerman, B. M.; Komissarova, N. G.; Zelenova, L. M.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 283 - 291
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 2 p. 321 - 332
反应条件
bis(acetylacetonate)nickel(II); SCl2; diisobutylaluminium hydride
1) hexane, 5 deg C, 20 h, 2) toluene, r.t., 2 h; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Tolstikov, G. A.; Lerman, B. M.; Komissarova, N. G.; Zelenova, L. M.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 283 - 291
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 2 p. 321 - 332
反应条件
sodium hydroxide; sodium tetrahydroborate; SCl2
1) hexane, 5 deg C, 20 h, 2) DMFA, H2O, 50-55 deg C, 2 h; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Tolstikov, G. A.; Lerman, B. M.; Komissarova, N. G.; Zelenova, L. M.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 283 - 291
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 2 p. 321 - 332
反应条件
SCl2; diisobutylaluminium hydride
multistep reaction, various reducing agents, various solvents; Product distribution;
参考文献
Tolstikov, G. A.; Lerman, B. M.; Komissarova, N. G.; Zelenova, L. M.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 283 - 291
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 2 p. 321 - 332
