乙酰溴-α-D-葡萄糖合成路线 （共 502 条）
反应条件
1: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide With N,N-dimethylimidazolone; ethylene glycol dimethyl ether; nickel dichloride T=20°C; 0.333333 h; 2: MeZnI 12 h; Title compound not separated from byproducts;
参考文献
Gong, Hegui; Sinisi, Riccardo; Gagne, Michel R.
Journal of the American Chemical Society, 2007 , vol. 129, # 7 p. 1908 - 1909
反应条件
bis(1,5-cyclooctadiene)nickel (0); NH4Br; zinc; Pybox in N,N-dimethyl acetamide T=25°C; 12 h; Inert atmosphere;
参考文献
Gong, Hegui; Andrews, R. Stephen; Zuccarello, Joseph L.; Lee, Stephen J.; Gagne, Michel R.
Organic Letters, 2009 , vol. 11, # 4 p. 879 - 882
反应条件
[Cp2Ti(III)Cl]2; acrylic acid methyl ester in tetrahydrofuran Ambient temperatureother reagents: (Cp2TiCl)2/methyl vinyl ketone, (Cp2TiCl)2/acrylonitrile;
参考文献
Spencer, Roxanne P.; Schwartz, Jeffrey
Journal of Organic Chemistry, 1997 , vol. 62, # 13 p. 4204 - 4205
反应条件
manganese; chloro-trimethyl-silane; bis(cyclopentadienyl)titanium dichloride in tetrahydrofuran T=20°C; 12 h; Product distribution; Further Variations:Reaction partnersquantity of catalyst;
参考文献
Hansen; Daasbjerg; Skrydstrup
Tetrahedron Letters, 2000 , vol. 41, # 44 p. 8645 - 8649
反应条件
[Cp2Ti(III)Cl]2 in tetrahydrofuran Ambient temperature;
参考文献
Spencer, Roxanne P.; Schwartz, Jeffrey
Journal of Organic Chemistry, 1997 , vol. 62, # 13 p. 4204 - 4205
反应条件
samarium diiodide in tetrahydrofuran Ambient temperatureslow addition of SmI2; Yield given;
参考文献
Doisneau, Gilles; Beau, Jean-Marie
Tetrahedron Letters, 1998 , vol. 39, # 21 p. 3477 - 3480
反应条件
[Cp2Ti(III)Cl]2 in tetrahydrofuran Ambient temperatureother glycosyl halides, other unsaturated organic compounds; Mechanism;
参考文献
Spencer, Roxanne P.; Schwartz, Jeffrey
Journal of Organic Chemistry, 1997 , vol. 62, # 13 p. 4204 - 4205
反应条件
N(Et)4ClO4 in acetonitrile T=20°C; Electrochemical reaction;
参考文献
Guerrini, Marco; Guglieri, Sara; Santarsiero, Roberto; Vismara, Elena
Tetrahedron Asymmetry, 2005 , vol. 16, # 1 p. 243 - 253
反应条件
tetraethylammonium iodide; N(Et)4ClO4 in acetonitrile Arylation; ElectrolysisAg cathode; controlled potential; Further byproducts given;
参考文献
Rondinini, Sandra; Mussini, Patrizia R.; Cantu, Giovanni; Sello, Guido
Physical Chemistry Chemical Physics, 1999 , vol. 1, # 12 p. 2989 - 2995
反应条件
copper(l) iodide 1.) ether, -35 deg C, 15 min, 2.) -25 deg C, 70 h; Multistep reaction. Yields of byproduct given;
参考文献
Bihovsky Ron; Selick Caryn; Giusti Irena
Journal of Organic Chemistry, 1988 , vol. 53, # 17 p. 4026 - 4031
