乙酰溴-α-D-葡萄糖合成路线 （共 502 条）
反应条件
1: 95 percent / acetone / 0.5 h / Heating 2: 96 percent / K2CO3, NaHSO3 / acetone; H2O / Ambient temperature 3: NaOH / methanol / Ambient temperature View Scheme
参考文献
Saito, Setsuo; Tsuchiya, Tomofusa
Chemical & Pharmaceutical Bulletin, 1985 , vol. 33, # 2 p. 503 - 508
反应条件
1: (E)-1-(3,5-dihydroxyphenyl)-2-(4-hydroxyphenyl)-ethene With sodium methylate in methanol T=20°C; 1.5 h; 2: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide in methanol T=40°C; 1 h;
参考文献
Brandolini, Vincenzo; Maietti, Annalisa; Tedeschi, Paola; Durini, Elisa; Vertuani, Silvia; Manfredini, Stefano
Journal of Agricultural and Food Chemistry, 2002 , vol. 50, # 25 p. 7407 - 7411
反应条件
1: 38 percent / Ag2CO3 / acetonitrile / 8 h / 20 °C 2: 98 percent / DMAP; pyridine / CH2Cl2 / 0.5 h 3: 40 percent / Pd(OAc)2; benzyltriethylammonium chloride; Bu3N / acetonitrile / 1.5 h / 85 °C 4: 94 percent / NaOMe / methanol / 1 h / 20 °C View Scheme
参考文献
Orsini, Fulvia; Pelizzoni, Francesca; Bellini, Barbara; Miglierini, Giuliana
Carbohydrate Research, 1997 , vol. 301, # 3-4 p. 95 - 109
反应条件
1: 95 percent / acetone / 0.5 h / Heating 2: 94 percent / K2CO3, NaHSO3 / acetone; H2O / Ambient temperature 3: NaOH / methanol / Ambient temperature View Scheme
参考文献
Saito, Setsuo; Tsuchiya, Tomofusa
Chemical & Pharmaceutical Bulletin, 1985 , vol. 33, # 2 p. 503 - 508
反应条件
1: 70 percent / lithium carbonate / CH2Cl2 / 16 h / 30 °C 2: 65 percent / sodium methoxide / methanol / 24 h / 20 °C View Scheme
参考文献
Pigman; Richtmyer
Journal of the American Chemical Society, 1942 , vol. 64, p. 369,372
反应条件
1: 95 percent / acetone / 0.5 h / Heating 2: 94 percent / K2CO3, NaHSO3 / acetone; H2O / Ambient temperature 3: NaOH / methanol / Ambient temperature View Scheme
参考文献
Chemical & Pharmaceutical Bulletin, , vol. 33, # 2 p. 503 - 508
反应条件
mercury(II) cyanide in dichloromethane 24 h;
参考文献
Leigh; Smart; Truscello
Carbohydrate Research, 1995 , vol. 276, # 2 p. 417 - 424
反应条件
sodium hydroxide; tetrabutylammomium bromide in benzene 0.5 h; Ambient temperature;
参考文献
Bogusiak, Jadwiga; Szeja, Wieslaw
Polish Journal of Chemistry, 1985 , vol. 59, # 3 p. 293 - 298
参考文献
Rao, Vanga S.; Perlin, Arthur S.
Carbohydrate Research, 1981 , vol. 92, p. 141 - 148
反应条件
1: 75 percent / acetone / 4 h / Heating 2: 1.) Bu4NOH, 2.) Ac2O, pyridine / 1.) dioxane, H2O, 25 deg C, 5 min, 2.) 8 h View Scheme
参考文献
Itsou, Fujimaki; Yoshitaka, Ichikawa; Hiroyoshi, Kuzuhara
Carbohydrate Research, 1982 , vol. 101, p. 148 - 151
