乙酰溴-α-D-葡萄糖合成路线 （共 502 条）
反应条件
1.1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C / Inert atmosphere 2.1: methanol; sodium methylate / tetrahydrofuran / 20 °C 3.1: sodium hypochlorite; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; tetrabutylammomium bromide; potassium carbonate; potassium bromide / dichloromethane / 1 h 3.2: 12 h View Scheme
参考文献
Kajjout, Mohammed; Zemmouri, Rajae; Rolando, Christian
Tetrahedron Letters, 2011 , vol. 52, # 37 p. 4738 - 4740
反应条件
1: With potassium carbonate in dimethyl sulfoxide Koenigs-Knorr reaction; 2: With sodium methylate in methanol T=20°C; 0.333333 h;
参考文献
Murota, Kaeko; Mitsukuni, Yuki; Ichikawa, Mami; Tsushida, Tojiro; Miyamoto, Sayuri; Terao, Junji
Journal of agricultural and food chemistry, 2004 , vol. 52, # 7 p. 1907 - 1912
反应条件
1.1: potassium carbonate / N,N-dimethyl-formamide / 6 h / Inert atmosphere 2.1: potassium carbonate / N,N-dimethyl-formamide / 12 h / 20 °C 3.1: sodium methylate / tetrahydrofuran; methanol / 20 °C 3.2: ion-exchange resin / 0.5 h 4.1: Pearlman's catalist; hydrogen / tetrahydrofuran; ethanol / 12 h View Scheme
参考文献
Kajjout, Mohammed; Rolando, Christian
Tetrahedron, 2011 , vol. 67, # 25 p. 4731 - 4741
反应条件
1: tetrabutylammonium hydrogen sulphate (TBAHS), 1 M aq. NaOH / CH2Cl2 / 25 °C 2: 100 percent / NaOMe / methanol View Scheme
参考文献
Melvin; McNeill; Henderson; Herbert
Tetrahedron Letters, 1999 , vol. 40, # 6 p. 1201 - 1202
反应条件
1.1: diphenyltin dichloride / tetrahydrofuran / 0.17 h / 20 °C 1.2: 24 h / 20 - 30 °C 2.1: methanol; sodium methylate / 1 h / 0 - 20 °C View Scheme
参考文献
Muramatsu, Wataru; Yoshimatsu, Hirofumi
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 13 p. 2518 - 2524
反应条件
1: Et3N; Bu4NBr / 1,2-dichloro-ethane / 16 h / 75 °C 2: K2CO3 / methanol / 2 h 3: 3.03 g / KOH / dimethylsulfoxide / 48 h View Scheme
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 70, # 4 p. 487 - 506
反应条件
1: 77.3 percent / NaN3 / dimethylformamide / 3.5 h / 50 °C 2: 99 percent / NaOMe / 1,2-dimethoxy-ethane; methanol / 1.5 h / 15 °C View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 47, # 2 p. 281 - 285
反应条件
1.1: tetrabutylammomium bromide; sodium hydroxide / dichloromethane / 18 h / 20 °C 2.1: sodium methylate / methanol / 18 h / 20 °C 2.2: Amberlite IR-120 (H+ form) View Scheme
参考文献
Peltier-Pain, Pauline; Marchillo, Karen; Zhou, Maoquan; Andes, David R.; Thorson, Jon S.
Organic Letters, 2012 , vol. 14, # 19 p. 5086 - 5089
反应条件
1: sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate / dichloromethane; water / 20 °C 2: sodium methylate / methanol / 20 °C View Scheme
参考文献
Ramos-Soriano, Javier; Niss, Ulf; Angulo, Jesus; Angulo, Manuel; Moreno-Vargas, Antonio J.; Carmona, Ana T.; Ohlson, Sten; Robina, Inmaculada
Chemistry - A European Journal, 2013 , vol. 19, # 52 p. 17989 - 18003
反应条件
1: 84 percent / HgO, HgBr2, CaSO4 / CHCl3 / 48 h / Ambient temperature 2: 90 percent / CH3ONa / methanol / 3 h View Scheme
参考文献
Kajimoto, Tetsuya; Ishioka, Yuichi; Katoh, Takahiro; Node, Manabu
Bioorganic and Medicinal Chemistry Letters, 2006 , vol. 16, # 22 p. 5736 - 5739
