乙酰溴-α-D-葡萄糖合成路线 （共 502 条）
反应条件
1: 59 percent / tetrabutylammonium bromide; aqueous sodium hydroxide / CH2Cl2 / 0.75 h / 20 °C 2: 93 percent / sodium methoxide / methanol / 0.25 h / 20 °C View Scheme
参考文献
Kroeger, Lars; Thiem, Joachim
Journal of Carbohydrate Chemistry, 2003 , vol. 22, # 1 p. 9 - 24
反应条件
1: 76 percent / 4 Angstroem molecular sieves, silver carbonate / CH2Cl2 / 72.5 h 2: K2CO3 / methanol / 4.5 h 3: NaH / dimethylformamide / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 61, # 16 p. 5280 - 5289
反应条件
1: potassium carbonate; tetrabutylammomium bromide / methanol; water; dichloromethane / 68 h / 20 °C 2: β-glucosidase from almonds; water / aq. phosphate buffer / 0.67 h / 37 °C / pH 7.4 / |Enzymatic reaction View Scheme
参考文献
Oliveri, Valentina; Viale, Maurizio; Caron, Giulia; Aiello, Cinzia; Gangemi, Rosaria; Vecchio, Graziella
Dalton Transactions, 2013 , vol. 42, # 6 p. 2023 - 2034
反应条件
1: potassium carbonate; tetrabutylammomium bromide / methanol; water; dichloromethane / 68 h / 20 °C 2: β-glucosidase from almonds; water / aq. phosphate buffer / 0.67 h / 37 °C / pH 7.4 / |Enzymatic reaction View Scheme
参考文献
Oliveri, Valentina; Viale, Maurizio; Caron, Giulia; Aiello, Cinzia; Gangemi, Rosaria; Vecchio, Graziella
Dalton Transactions, 2013 , vol. 42, # 6 p. 2023 - 2034
反应条件
1: acetone; aqueous KOH-solution
2: barium hydroxide; water
View Scheme
参考文献
Zemplen et al.
Chemische Berichte, 1944 , vol. 77/79, p. 452,455
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
参考文献
Giese, Bernd; Gilges, Stefan; Groeninger, Kay S.; Lamberth, Clemens; Witzel, Tom
Liebigs Annalen der Chemie, 1988 , p. 615 - 617
反应条件
2,2'-azo-bisisobutyronitrile; sodium cyanoborohydride in acetonitrile
T=80°C; 6.5 h; Inert atmosphere;
参考文献
Bruyere, Isabelle; Toth, Zoltan; Benyahia, Hamida; Xue, Jia Lu; Praly, Jean-Pierre
Tetrahedron, 2013 , vol. 69, # 46 p. 9656 - 9662
反应条件
sodium cyanoborohydride in tert-butyl alcohol
0.583333 h; Irradiation;
参考文献
Praly, Jean-Pierre; Ardakani, Azin Salek; Bruyere, Isabelle; Marie-Luce, Chrystelle; Bing Qin, Bing
Carbohydrate Research, 2002 , vol. 337, # 18 p. 1623 - 1632
反应条件
sodium cyanoborohydride in tert-butyl alcohol
0.5 h; UV-irradiation;
参考文献
Bruyere, Isabelle; Toth, Zoltan; Benyahia, Hamida; Xue, Jia Lu; Praly, Jean-Pierre
Tetrahedron, 2013 , vol. 69, # 46 p. 9656 - 9662
反应条件
sodium cyanoborohydride; thiophenol in tert-butyl alcohol
1.75 h; Irradiation;
参考文献
Praly, Jean-Pierre; Ardakani, Azin Salek; Bruyere, Isabelle; Marie-Luce, Chrystelle; Bing Qin, Bing
Carbohydrate Research, 2002 , vol. 337, # 18 p. 1623 - 1632
