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乙二醇
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63148-62-9
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二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-甲氧基苯硼酸
合成路线
(共 1108 条)
1231261-82-7
+
5720-07-0
4-甲氧基苯硼酸
→
反应条件
58743-77-4
4-甲氧基-4’-氰基联苯
反应条件
1,3-bis-(diphenylphosphino)propane; potassium carbonate; nickel dichloride in 1,4-dioxane T=100°C; Suzuki-Miyaura coupling; Inert atmosphere;
参考文献
Zhao, Yu-Long; Li, You; Li, Yu; Gao, Lian-Xun; Han, Fu-She
Chemistry - A European Journal, 2010 , vol. 16, # 17 p. 4991 - 4994
5720-07-0
4-甲氧基苯硼酸
+
767-00-0
4-羟基苯甲腈
→
反应条件
58743-77-4
4-甲氧基-4’-氰基联苯
反应条件
1: 4-hydroxy-benzonitrile With potassium phosphate; triethylamine; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate in 1,4-dioxane T=100°C; 3 h; Inert atmosphere; 2: (4-methoxyphenyl)-boronic acid With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in 1,4-dioxane T=100 - 110°C; Suzuki-Miyaura coupling; Inert atmosphere;
参考文献
Chen, Guo-Jun; Huang, Jie; Gao, Lian-Xun; Han, Fu-She
Chemistry - A European Journal, 2011 , vol. 17, # 14 p. 4038 - 4042
→
反应条件
58743-77-4
4-甲氧基-4’-氰基联苯
+
71426-20-5
反应条件
palladium diacetate; cesium fluoride; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in tetrahydrofuran T=65°C; Suzuki-Miyaura reaction; 5 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 16, # 45 p. 13390 - 13397
5720-07-0
4-甲氧基苯硼酸
→
反应条件
763886-63-1
Gabazine Ethyl Ester
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / 0.5 h / 20 °C / |Inert atmosphere 2: N,N-dimethyl-formamide / 5 h / 80 °C View Scheme
参考文献
Rahman, Mohammad Mostafizur; Akiyoshi, Yuki; Furutani, Shogo; Matsuda, Kazuhiko; Furuta, Kenjiro; Ikeda, Izumi; Ozoe, Yoshihisa
Bioorganic and Medicinal Chemistry, 2012 , vol. 20, # 19 p. 5957 - 5964
585-70-6
5-溴-2-糠酸
+
5720-07-0
4-甲氧基苯硼酸
→
反应条件
52938-99-5
反应条件
ethylenediaminetetraacetic acid; potassium carbonate; palladium dichloride T=100°C; Suzuki-Miyaura reaction; 1 h;
参考文献
Korolev, Dmitrii N.; Bumagin, Nikolay A.
Tetrahedron Letters, 2005 , vol. 46, # 34 p. 5751 - 5754
49619-43-4
+
5720-07-0
4-甲氧基苯硼酸
→
反应条件
54118-74-0
反应条件
sodium carbonate; palladium dichloride in water; acetone T=20°C; Suzuki type reaction; 1.5 h; Inert atmosphere;
参考文献
Xin, Bing-Wei
Synthetic Communications, 2008 , vol. 38, # 16 p. 2826 - 2837
5720-07-0
4-甲氧基苯硼酸
+
609-65-4
→
反应条件
54118-74-0
反应条件
sodium lauryl sulfate; potassium carbonate; palladium dichloride in water T=60°C; 6 h;
参考文献
Xin, Bingwei; Zhang, Yuhong; Cheng, Kai
Synthesis, 2007 , # 13 p. 1970 - 1978
5720-07-0
4-甲氧基苯硼酸
+
118-91-2
→
反应条件
54118-74-0
反应条件
tetrakis(triphenylphosphine) palladium(0); water; N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline in N,N-dimethyl-formamide T=60°C; 15 h; Inert atmosphere;
参考文献
Kwon, Young Bum; Choi, Bo Ram; Lee, Seung Hwan; Seo, Jin-Soo; Yoon, Cheol Min
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 9 p. 2672 - 2674
5720-07-0
4-甲氧基苯硼酸
+
89-98-5
→
反应条件
54118-74-0
反应条件
3,3-dimethyl-butan-2-one; [Ru(CO)3Cl2]2; K3PO4*3H2O; [(t-Bu)3PH]BF4 in water; toluene T=100°C; 24 h; Inert atmosphere;
参考文献
Li, Hong; Xu, Yuan; Shi, Erbo; Wei, Wei; Suo, Xiangqiang; Wan, Xiaobing
Chemical Communications, 2011 , vol. 47, # 27 p. 7880 - 7882
5720-07-0
4-甲氧基苯硼酸
→
反应条件
626-02-8
反应条件
1.1: N-methyl-propane-1,3-diamine / toluene / 4 h / |Inert atmosphere; |Reflux; |Dean-Stark 1.2: 2.5 h / 0 - 20 °C / |Inert atmosphere; |Reflux 2.1: boron tribromide / dichloromethane / 12 h / 0 - 20 °C / |Inert atmosphere 3.1: dimethyl sulfoxide; water / 24 h / 120 °C View Scheme
参考文献
Lee, Chun-Young; Ahn, Su-Jin; Cheon, Cheol-Hong
Journal of Organic Chemistry, 2013 , vol. 78, # 23 p. 12154 - 12160
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