3-羟基-7,12-二甲基苯并(a)蒽合成路线 （共 13 条）
反应条件
lithium methylmercaptide in N,N-dimethyl-formamide
4 h; Heating;
参考文献
Sukumaran, K.B.; Harvey, Ronald G.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4407 - 4413
反应条件
1: 95 percent / NaBH4 / dimethylsulfoxide / 5 h / Ambient temperature
2: 95 percent / lithium thiomethoxide / dimethylformamide / 4 h / Heating
View Scheme
参考文献
Sukumaran, K.B.; Harvey, Ronald G.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4407 - 4413
反应条件
lithium aluminium tetrahydride; titanium(III) chloride in tetrahydrofuran
2 h; Heating; Yield given;
参考文献
Lee; Harvey
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3502 - 3507
反应条件
1: 1.) Mg, I2 / 1.) THF, reflux, 30 min, 2.) THF, reflux, 2 h
2: 50 percent / sulfuric acid, H2O / 1.5 h / 100 °C
3: 99 percent / benzene; diethyl ether / 16 h / Heating
4: TiCl3, LiAlH4 / tetrahydrofuran / 2 h / Heating
View Scheme
参考文献
Lee; Harvey
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3502 - 3507
反应条件
1: 99 percent / benzene; diethyl ether / 16 h / Heating
2: TiCl3, LiAlH4 / tetrahydrofuran / 2 h / Heating
View Scheme
参考文献
Lee; Harvey
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3502 - 3507
反应条件
1: 50 percent / sulfuric acid, H2O / 1.5 h / 100 °C
2: 99 percent / benzene; diethyl ether / 16 h / Heating
3: TiCl3, LiAlH4 / tetrahydrofuran / 2 h / Heating
View Scheme
参考文献
Lee; Harvey
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3502 - 3507
反应条件
1-iso-propyl-4-methylbenzene; palladium on activated charcoal
2.5 h; Heating;
参考文献
Sharma
Synthetic Communications, 1993 , vol. 23, # 3 p. 389 - 394
反应条件
hydrogenchloride in methanol
23 h; Ambient temperature;
参考文献
Sharma
Synthetic Communications, 1993 , vol. 23, # 3 p. 389 - 394
反应条件
potassium dihydrogenphosphate; adogen 464; Fremy’s salt in water; benzene
0.5 h;
参考文献
Sharma
Synthetic Communications, 1993 , vol. 23, # 3 p. 389 - 394
反应条件
1: 0.10 g / o-iodoxybenzoic acid / dimethylformamide / 0.17 h
2: NaBH4 / dimethylformamide
View Scheme
参考文献
Sukumaran, K.B.; Harvey, Ronald G.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4407 - 4413
