1,4-二氢-1,4-环氧萘合成路线 （共 84 条）
反应条件
parahydrogen; lt;Rh(Ph-β-Glup-OH)(COD)gt;BF4 in benzene-d6 in magnetic field; other catalyst: RhCl(PPh3)3; reaction followed in FT-NMR spectrometer; Mechanism;
参考文献
Wittig; Pohmer
Chemische Berichte, 1956 , vol. 89, p. 1334,1348
反应条件
1: 70 percent / NaHCO3 / toluene / 36 h / 145 °C 2: 91 percent / conc. HCl / methanol / 15 h / Heating 3: 81 percent / MCPBA / CHCl3 / Ambient temperature View Scheme
参考文献
Dehaen, Wim; Corens, David; L'Abbe, Gerrit
Synthesis, 1996 , # 2 p. 201 - 203
反应条件
1: 70 percent / NaHCO3 / toluene / 36 h / 145 °C 2: 91 percent / conc. HCl / methanol / 15 h / Heating 3: 81 percent / MCPBA / CHCl3 / Ambient temperature 4: 1.) CuI / 1.) THF, -15 deg C, 5 min, 2.) THF, RT, 24 h 5: 61 percent / o-chloranil / toluene / Heating View Scheme
参考文献
Dehaen, Wim; Corens, David; L'Abbe, Gerrit
Synthesis, 1996 , # 2 p. 201 - 203
反应条件
[Pt(PPh3)4] in hexane T=55°C; 10 h; stereoselective reaction;
参考文献
Yang, Dingqiao; Liang, Ni
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 13 p. 2080 - 2086
反应条件
copper(I) bromide dimethylsulfide complex; C36H30NO2P; boron trifluoride diethyl etherate in 1,2-dichloro-ethane
T=-40°C; 16 h; Inert atmosphere;
参考文献
Bos, Pieter H.; Rudolph, Alena; Perez, Manuel; Fananas-Mastral, Martin; Harutyunyan, Syuzanna R.; Feringa, Ben L.
Chemical Communications, 2012 , vol. 48, # 12 p. 1748 - 1750
反应条件
bis-triphenylphosphine-palladium(II) chloride; triethylamine; zinc(II) chloride; zinc in tetrahydrofuran
T=60°C; 13 h;
参考文献
Duan, Jiun-Pey; Cheng, Chien-Hong
Tetrahedron Letters, 1993 , vol. 34, # 25 p. 4019 - 4022
参考文献
Luo, Jihmei; Hart, Harold
Journal of Organic Chemistry, 1988 , vol. 53, # 6 p. 1341 - 1343
反应条件
1: 86 percent / lithium tri-tert-butoxyaluminodeuteride, Et3B / various solvent(s) / 0.5 h
2: 83 percent / Et3N / diethyl ether / 2 h / Ambient temperature
3: benzene-d6 / 2 h / 80 °C
View Scheme
参考文献
Moss, Randall J.; Rickborn, Bruce
Journal of Organic Chemistry, 1985 , vol. 50, # 9 p. 1381 - 1384
反应条件
(i), (ii) aq. HCl, Ac2O; Multistep reaction;
参考文献
Sugihashi,M. et al.
Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 2836 - 2841
反应条件
Ni(Br)2(dppe); zinc in acetonitrile
T=80°C; 12 h;
参考文献
Rayabarapu, Dinesh K.; Sambaiah, Thota; Cheng, Chien-Hong
Angewandte Chemie - International Edition, 2001 , vol. 40, # 7 p. 1286 - 1288
