4-丙烯基-2-甲氧基苯苄合成路线 （共 13 条）
反应条件
1: alkali 2: K2cr2O7; diluted sulfuric acid / Spaltung des entstandenen 3-Methoxy-4-benzyloxy-benzaldehyds mit rauchender Salzsaeure in der Kaelte View Scheme
参考文献
Boehringer and Soehne
Patent: DE65937 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 3, p. 897
反应条件
1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / acetone; water / 20 °C 2: 5 palladium on charcoal; hydrogen / methanol / 20 °C / |Inert atmosphere View Scheme
参考文献
Yadav, Yogesh; Owens, Eric A.; Sharma, Vibhuti; Aneja, Ritu; Henary, Maged
European Journal of Medicinal Chemistry, 2014 , vol. 75, p. 1 - 10
反应条件
1: ozone / dichloromethane / -78 °C 2: 2,4,6-trimethyl-pyridine; manganese; bis(cyclopentadienyl)titanium dichloride; chloro-trimethyl-silane / tetrahydrofuran / 7 h / Inert atmosphere View Scheme
参考文献
Rosales, Antonio; Munoz-Bascon, Juan; Lopez-Sanchez, Cristobal; Alvarez-Corral, Miriam; Munoz-Dorado, Manuel; Rodriguez-Garcia, Ignacio; Oltra, J. Enrique
Journal of Organic Chemistry, 2012 , vol. 77, # 8 p. 4171 - 4176
反应条件
1: ozone / dichloromethane / -78 °C 2: manganese; bis(cyclopentadienyl)titanium dichloride / tetrahydrofuran / 0.5 h / Inert atmosphere View Scheme
参考文献
Rosales, Antonio; Munoz-Bascon, Juan; Lopez-Sanchez, Cristobal; Alvarez-Corral, Miriam; Munoz-Dorado, Manuel; Rodriguez-Garcia, Ignacio; Oltra, J. Enrique
Journal of Organic Chemistry, 2012 , vol. 77, # 8 p. 4171 - 4176
反应条件
1: alkali 2: K2cr2O7; sulfuric acid View Scheme
参考文献
Boehringer and Soehne
Patent: DE65937 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 3, p. 897
反应条件
lithium bromide in dichloromethane T=30 - 35°C; 12 h; Inert atmosphere; regioselective reaction;
参考文献
Chakraborti, Asit K.; Chankeshwara, Sunay V.
Journal of Organic Chemistry, 2009 , vol. 74, # 3 p. 1367 - 1370
反应条件
formic acid; sodium formate; palladium on activated charcoal in methanol 4 h; Heating;
参考文献
Krishnamurty, H. G.; Ghosh, Sanjukta; Sathyanarayana, S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1986 , vol. 25, p. 1253 - 1254
反应条件
1: ethanolic KOH 2: tetrachloromethane; bromine / unter Kuehlung View Scheme
参考文献
v. Fodor
Chemische Berichte, 1943 , vol. 76, p. 1216,1217, 1219
反应条件
1: 2-methoxy-4-(2-propenyl)-phenol With sodium hydride in N,N-dimethyl-formamide
T=0°C; 0.5 h;
2: benzyl bromide in N,N-dimethyl-formamide
T=0°C; 1 h;
参考文献
Sun, Bing-Feng; Hong, Ran; Kang, Yan-Biao; Deng, Li
Journal of the American Chemical Society, 2009 , vol. 131, # 30 p. 10384 - 10385
反应条件
1: |Inert atmosphere
2: sodium hydride / N,N-dimethyl-formamide / 20 °C / |Inert atmosphere
View Scheme
参考文献
Hemelaere, Remy; Caijo, Frederic; Mauduit, Marc; Carreaux, Francois; Carboni, Bertrand
European Journal of Organic Chemistry, 2014 , vol. 2014, # 16 p. 3328 - 3333
