1-(4-甲氧基苯基)-3-苯基-丙-1-酮合成路线 （共 53 条）
反应条件
potassium phosphate; platinacycle; pentan-3-one in toluene T=90 - 100°C;
参考文献
Liao, Yuan-Xi; Hu, Qiao-Sheng
Journal of Organic Chemistry, 2010 , vol. 75, # 20 p. 6986 - 6989
反应条件
[RuCl(η5-3-phenylindenyl)(PPh3)] in toluene T=20°C; 2.5 h;
参考文献
Manzini, Simone; Poater, Albert; Nelson, David J.; Cavallo, Luigi; Nolan, Steven P.
Chemical Science, 2013 , vol. 5, # 1 p. 180 - 188
反应条件
1: COgen With tri-tert-butyl phosphine; N-ethyl-N,N-diisopropylamine; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane Inert atmosphere; 2: styrene; para-iodoanisole With N,N-dicyclohexylmethylamine; di-(1-adamantyl)-n-butylphosphine in 1,4-dioxane T=95°C; Heck reaction; 20 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 13, # 9 p. 2444 - 2447
反应条件
potassium phosphate; Wilkinson's catalyst; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in 1,4-dioxane T=60°C; 20 h; Inert atmosphere;
参考文献
Jiang, Quanbin; Guo, Tenglong; Wang, Qingfu; Wu, Ping; Yu, Zhengkun
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 9 p. 1874 - 1880
反应条件
[(C6H6)(PCy3)(CO)RuH]+BF4-; cyclopentene in toluene T=120°C; 12 h; Inert atmosphereSchlenk technique;
参考文献
Kalutharage, Nishantha; Yi, Chae S.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 51 p. 13651 - 13655
Angew. Chem., 2013 , vol. 125, # 51 p. 13896 - 13900
反应条件
1: potassium hydride / tetrahydrofuran / 50 °C 2: PdCl(C6H4C6H4NH2)(P(C10H15)2C4H9); cesium hydroxide monohydrate; CPME / 24 h / 105 °C / |Sealed tube 3: palladium on activated charcoal; hydrogen / ethanol / 20 °C / 760.05 Torr 4: 1-methoxy-4-chlorobenzene; caesium carbonate; palladium diacetate; dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine / water; tert-butyl alcohol / 16 h / 95 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 134, # 40 p. 16856 - 16868,13
Journal of the American Chemical Society, , vol. 134, # 40 p. 16856 - 16868
反应条件
1: ICyCuCl; sodium t-butanolate / toluene / 1.5 h / 20 °C / |Inert atmosphere 2: methanol; water / 0 - 20 °C 3: potassium hydride / tetrahydrofuran / 50 °C 4: PdCl(C6H4C6H4NH2)(P(C10H15)2C4H9); cesium hydroxide monohydrate; CPME / 24 h / 105 °C / |Sealed tube 5: palladium on activated charcoal; hydrogen / ethanol / 20 °C / 760.05 Torr 6: 1-methoxy-4-chlorobenzene; caesium carbonate; palladium diacetate; dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine / water; tert-butyl alcohol / 16 h / 95 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 134, # 40 p. 16856 - 16868,13
Journal of the American Chemical Society, , vol. 134, # 40 p. 16856 - 16868
反应条件
1: PdCl(C6H4C6H4NH2)(P(C10H15)2C4H9); cesium hydroxide monohydrate; CPME / 24 h / 105 °C / |Sealed tube 2: palladium on activated charcoal; hydrogen / ethanol / 20 °C / 760.05 Torr 3: 1-methoxy-4-chlorobenzene; caesium carbonate; palladium diacetate; dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine / water; tert-butyl alcohol / 16 h / 95 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 134, # 40 p. 16856 - 16868,13
Journal of the American Chemical Society, , vol. 134, # 40 p. 16856 - 16868
反应条件
tris(triphenylphosphine)ruthenium(II) chloride; potassium hydroxide in 1,4-dioxane T=80°C; 40 h;
参考文献
Applied Organometallic Chemistry, , vol. 25, # 9 p. 695 - 698
反应条件
sodium hydrogen telluride; 18-crown-6 ether in tetrahydrofuran; ethanol Ambient temperature;
参考文献
Huang, Xian; Pi, Jin-Hong
Synthetic Communications, 1990 , vol. 20, # 15 p. 2297 - 2300
