2-(烯丙基氨基)苯甲酸合成路线 （共 10 条）
反应条件
potassium phosphate; copper(l) iodide; 1,1'-binaphthyl-2,2'-diol in N,N-dimethyl-formamide
T=25°C; Ullmann reaction; 16 h; Inert atmosphere;
参考文献
Zeng, Liang; Fu, Hua; Qiao, Renzhong; Jiang, Yuyang; Zhao, Yufen
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 10 p. 1671 - 1676
反应条件
potassium phosphate; copper(l) iodide; 1,1'-binaphthyl-2,2'-diol in N,N-dimethyl-formamide
T=25°C; Ullmann reaction; 16 h; Inert atmosphere;
参考文献
Zeng, Liang; Fu, Hua; Qiao, Renzhong; Jiang, Yuyang; Zhao, Yufen
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 10 p. 1671 - 1676
反应条件
palladium diacetate; diphenylphosphinobenzene-3-sulfonic acid sodium salt in tetrahydrofuran; water
T=20°C;
参考文献
Hikawa, Hidemasa; Yokoyama, Yuusaku
Journal of Organic Chemistry, 2011 , vol. 76, # 20 p. 8433 - 8439
反应条件
potassium phosphate; copper(l) iodide; 1,1'-binaphthyl-2,2'-diol in N,N-dimethyl-formamide
T=25°C; Ullmann reaction; 16 h; Inert atmosphere;
参考文献
Zeng, Liang; Fu, Hua; Qiao, Renzhong; Jiang, Yuyang; Zhao, Yufen
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 10 p. 1671 - 1676
反应条件
sodium hydride in N,N-dimethyl-formamide
1) 0-5 deg C, 15 min, 2) r.t. 18 h;
参考文献
Coppola, Gary M.
Journal of Heterocyclic Chemistry, 1980 , vol. 17, p. 1785 - 1787
反应条件
1: With dihydrogen peroxide; sodium hydroxide in water
T=30°C; Cooling with ice;
2: With acetic acid in water
pH=5 - 6; Cooling with ice;
参考文献
Wang, Yao; Zhang, Mei; Cao, Shengli; Lin, Huihui; Gao, Man; Li, Zhongfeng
Synthetic Communications, 2012 , vol. 42, # 18 p. 2715 - 2727
反应条件
1.1: potassium carbonate / N,N-dimethyl-formamide
2.1: dihydrogen peroxide; sodium hydroxide / water / 30 °C / Cooling with ice
2.2: pH 5 - 6 / Cooling with ice
View Scheme
参考文献
Wang, Yao; Zhang, Mei; Cao, Shengli; Lin, Huihui; Gao, Man; Li, Zhongfeng
Synthetic Communications, 2012 , vol. 42, # 18 p. 2715 - 2727
反应条件
zinc
1.) DMF, r.t., 15 min, 2.) DMF, r.t., 70 min; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Kumar, H. M. Samapath; Anjaneyulu, S.; Reddy, B. V. Subba; Yadav, J. S.
Synlett, 1999 , # 5 p. 551 - 552
反应条件
water; potassium carbonate
参考文献
Houben; Brassert
Chemische Berichte, 1906 , vol. 39, p. 3234
反应条件
ethanol; potassium carbonate
参考文献
Dominikiewicz; Kijewska
Archiwum Chemji i Farmacji, 1939 , vol. 4, p. 8,15, 16
Chem.Abstr., 1940 , p. 740
