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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
57479-09-1
合成路线
（共 8 条）
5332-24-1
3-溴喹啉
→
反应条件
57479-09-1
反应条件
1: triallyl(2-methylphenyl)silane With tetrabutyl ammonium fluoride in water; dimethyl sulfoxide T=20°C; 1 h; 2: 3-(bromo)-quinoline With tri-cyclo-hexyl-phosphine; palladium dichloride in water; dimethyl sulfoxide T=80°C; 20 h;
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
5332-24-1
3-溴喹啉
+
16419-60-6
2-甲基苯硼酸
→
反应条件
57479-09-1
反应条件
K3PO4*7H2O; palladium diacetate in ethylene glycol T=80°C; Suzuki coupling; 1.41667 h;
参考文献
Liu, Chun; Han, Na; Song, Xiaoxiao; Qiu, Jieshan
European Journal of Organic Chemistry, 2010 , # 29 p. 5548 - 5551
10174-55-7
1-乙酰基-1,2-二氢喹啉
+
16419-60-6
2-甲基苯硼酸
→
反应条件
57479-09-1
反应条件
palladium diacetate; copper(II) bis(trifluoromethanesulfonate); silver(l) oxide in toluene T=110°C; Inert atmosphereSealed tube; regioselective reaction;
参考文献
Tiwari, Virendra Kumar; Pawar, Govind Goroba; Das, Riki; Adhikary, Amit; Kapur, Manmohan
Organic Letters, 2013 , vol. 15, # 13 p. 3310 - 3313
5332-24-1
3-溴喹啉
+
7029-31-4
→
反应条件
57479-09-1
反应条件
[(P{(NC5H10)(C6H11)2})2Pd(Cl)2] in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=100°C; Negishi cross-coupling reaction; 0.0833333 h; In air;
参考文献
Bolliger, Jeanne L.; Frech, Christian M.
Chemistry - A European Journal, 2010 , vol. 16, # 36 p. 11072 - 11081
95-46-5
邻溴甲苯
→
反应条件
57479-09-1
反应条件
potassium hydroxide; tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide in tetrahydrofuran 8 h; Heating;
参考文献
Ishikura, Minoru; Oda, Izumi; Terashima, Masanao
Heterocycles, 1985 , vol. 23, # 9 p. 2375 - 2386
91-22-5
喹啉
→
反应条件
57479-09-1
反应条件
1: sodium tetrahydroborate / acetic acid / 2 h / 0 - 50 °C / |Inert atmosphere 2: palladium diacetate; copper(II) bis(trifluoromethanesulfonate); silver(l) oxide / toluene / 110 °C / |Inert atmosphere; |Sealed tube View Scheme
参考文献
Tiwari, Virendra Kumar; Pawar, Govind Goroba; Das, Riki; Adhikary, Amit; Kapur, Manmohan
Organic Letters, 2013 , vol. 15, # 13 p. 3310 - 3313
932-31-0
邻甲苯基溴化镁
→
反应条件
57479-09-1
反应条件
1.1: silicon tetrachloride / diethyl ether / -20 - 20 °C 2.1: 3.5 g / diethyl ether / 12 h / Heating 3.1: tetrabutylammonium fluoride trihydrate / dimethylsulfoxide; H2O / 1 h / 20 °C 3.2: 80 percent / PCy3 / PdCl2 / dimethylsulfoxide; H2O / 20 h / 80 °C View Scheme
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
13835-81-9
→
反应条件
57479-09-1
反应条件
1.1: 3.5 g / diethyl ether / 12 h / Heating 2.1: tetrabutylammonium fluoride trihydrate / dimethylsulfoxide; H2O / 1 h / 20 °C 2.2: 80 percent / PCy3 / PdCl2 / dimethylsulfoxide; H2O / 20 h / 80 °C View Scheme
参考文献
Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1715 - 1727
