1: 1.) BF3*Et2O, 2.) aq. NaBF4 / 1.) CH2Cl2, 0 deg C, 0.25 h, 2.) CH2Cl2, 15 min 2: Et3N / tetrahydrofuran / 10 h / 60 °C View Scheme

potassium tert-butylate in tetrahydrofuran T=-78°C; 18 h; var. dialkyl ketones, var. reactant stoichiometries, var. solvents and times; rel. reactivity for C-H insertion; Product distribution;

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T=60°C; 10 h; other substituted phenyliodonium tetrafluoroborates, other amines, var. temp. and time; Product distribution;