1,1,3,4-四甲基-1-锗杂-3-环戊烯合成路线 （共 36 条）
反应条件
in benzene
Irradiation (UV/VIS); sealed NMR tube; irradn. (450 W Hg lamp, room temp., 30 min); detd. by NMR and MS spectroscopy;
参考文献
Mochida, Kunio; Akazawa, Miyuki; Goto, Midori; Sekine, Akiko; Ohashi, Yuji; Nakadaira, Yasuhiro
Organometallics, 1998 , vol. 17, # 9 p. 1782 - 1789
反应条件
in cyclohexane
Kinetics; Irradiation (UV/VIS); 110-W low pressure Hg arc, under Ar, room temp.; GC-MS;
参考文献
Mochida, Kunio; Yoneda, Isao; Wakasa, Masanobu
Journal of Organometallic Chemistry, 1990 , vol. 399, # 1/2 p. 53 - 62
反应条件
in tetrahydrofuran
byproducts: LiCl; Sonication; (Ar); sonication for 15 min; filtration; distn.;
参考文献
Lei, Deqing; Gaspar, Peter P.
Polyhedron, 1991 , vol. 10, p. 1221 - 1226
反应条件
in benzene
Irradiation (UV/VIS); irradn. (450 W Hg lamp, 3 h);
参考文献
Mochida, Kunio; Akazawa, Miyuki; Goto, Midori; Sekine, Akiko; Ohashi, Yuji; Nakadaira, Yasuhiro
Organometallics, 1998 , vol. 17, # 9 p. 1782 - 1789
反应条件
in perdeuterocyclohexane
Kinetics; byproducts: 2-phenyl-1,3-butadiene; Irradiation (UV/VIS); photolysis of 0.03-0.05 M soln. of 1,1-dimethyl-3-phenylgermacyclopent-3-ene in cyclohexane-d12 containing 2,3-dimethyl-1,3-butadiene at 25°C; monitoring by GC and NMR;
参考文献
Leigh, William J.; Lollmahomed, Farahnaz; Harrington, Cameron R.
Organometallics, 2006 , vol. 25, # 8 p. 2055 - 2065
反应条件
in cyclohexane
Irradiation (UV/VIS); Irradn. with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 6 h.; GC-MS.;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 9 p. 2772 - 2777
反应条件
in cyclohexane
Irradiation (UV/VIS); Photolyzing with a 110-W medium-pressure Hg arc lamp;
参考文献
Mochida, Kunio; Wakasa, Masanobu; Nakadaira, Yasuhiro; Sakaguchi, Yoshio; Hayashi, Hisaharu
Organometallics, 1988 , vol. 7, p. 1869 - 1871
反应条件
in tetrahydrofuran
Kinetics; Irradiation (UV/VIS); flash photolysis (266 nm), 293 K, quenching with 2,3-dimethylbutadiene;
参考文献
Mochida, Kunio; Wakasa, Masanobu; Nakadaira, Yasuhiro; Sakaguchi, Yoshio; Hayashi, Hisaharu
Organometallics, 1988 , vol. 7, p. 1869 - 1871
反应条件
in deuterated toluene
byproducts: benzene; heating a soln. of germanium compd. in toluene-d8 at 80°C for 30 min; not isolated, detected by NMR and GC-MS;
参考文献
Mochida, Kunio; Matsuhisa, Nao; Sato, Ryuji; Nakadaira, Yasuhiro
Organometallics, 2006 , vol. 25, # 17 p. 4231 - 4233
反应条件
in neat (no solvent)
heating in sealed tube, 150°C for 2h;;
参考文献
Barrau, Jacques; Rima, Ghassoub; Cassano, Valerie
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992 , vol. 22, p. 1431 - 1444
