in neat (no solvent)
Ge deriv. heating with a large excess of organic reagent in a sealed tube at 130°C for 8 h, concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
in neat (no solvent)
Ge deriv. heating with a large excess of organic reagent in a sealed tube at 200°C for 6 h, concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
in perdeuterocyclohexane
byproducts: C2H4, C3H6; Irradiation (UV/VIS); photolysis at 254 nm of germanium compd. in cyclohexane-d12 in presence of butadiene deriv.; NMR and GC/MS;
参考文献
Leigh, William J.; Potter, Gregory D.; Huck, Lawrence A.; Bhattacharya, Adroha
Organometallics, 2008 , vol. 27, # 22 p. 5948 - 5959
in neat (no solvent)
Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
in hexane
Irradiation (UV/VIS); further products; (Ar); SiGe compd. in hexane was mixed with 1,3-dimethyl-2,3-butadiene; photolyzed for 1 h in quartz sealed tubes; GC, GC/MS, PMR monitoring; not isolated;
参考文献
Leigh, William J.; Toltl, Nicholas P.; Apodaca, Paula; Castruita, Madeli; Pannell, Keith H.
Organometallics, 2000 , vol. 19, # 16 p. 3232 - 3241
in diethyl ether
under N2, to suspn. of Ph3PGeI2 and CH2=CMeCMe=CH2 in ether PhLi (0.45 M soln. in ether) added dropwise at -70°C, after 1 h warmed to room temp., hydrolyzed; dried, analyzed by gas chromy.;
参考文献
Inoguchi, Yoshio; Okui, Shuko; Mochida, Kunio; Itai, Akiko
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 3 p. 974 - 977
in perdeuterocyclohexane
byproducts: 2,3-dimethyl-1,3-butadiene; Irradiation (UV/VIS); photolysis of a soln. of germanium compd. in C6D12 with isoprene at 254 nm;
参考文献
Leigh, William J.; Harrington, Cameron R.; Vargas-Baca, Ignacio
Journal of the American Chemical Society, 2004 , vol. 126, # 49 p. 16105 - 16116
isoprene in cyclohexane-d12
byproducts: 2,3-dimethyl-1,3-butadiene; Irradiation (UV/VIS); under Ar; soln. of Ge compd. in cyclohexane-d12 contg. isoprene subjected to photolysis at 25 and 51°C; not isolated; monitored by (1)H NMR and mass spectra; Ph2GeC4H5CH3, CH3C(CH2)C(CH2)CH3 and Ge-contg. oligomeric compds. obtained;
参考文献
Huck, Lawrence A.; Leigh, William J.
Organometallics, 2009 , vol. 28, # 23 p. 6777 - 6788
