3,4-二氢苯并[a]蒽-1(2h)-酮合成路线 （共 15 条）
反应条件
(i) Mg, (ii) /BRN= 1975442/, (iii) (heating); Multistep reaction;
参考文献
Vingiello,F.A. et al.
Journal of Organic Chemistry, 1971 , vol. 36, # 15 p. 2053 - 2056
反应条件
methanesulfonic acid
T=90°C; 2 h;
参考文献
Wiznycia, Alexander V.; Desper, John; Levy, Christopher J.
Dalton Transactions, 2007 , # 15 p. 1520 - 1527
反应条件
1: 87 percent / Pd/C / various solvent(s) / 40 h / Heating
2: 100 percent / methanesulfonic acid / 2 h / 90 °C
View Scheme
参考文献
Wiznycia, Alexander V.; Desper, John; Levy, Christopher J.
Dalton Transactions, 2007 , # 15 p. 1520 - 1527
反应条件
1: hydrazine monohydrate; potassium hydroxide / bis-(2-hydroxy-ethyl) ether / 8 h / 200 °C
2: sulfuric acid / 18 h / Heating
3: 100 percent / methanesulfonic acid / 2 h / 90 °C
View Scheme
参考文献
Wiznycia, Alexander V.; Desper, John; Levy, Christopher J.
Dalton Transactions, 2007 , # 15 p. 1520 - 1527
反应条件
1: aluminum chloride / 1,2-dichloro-ethane / 2 h / 20 °C
2: hydrazine monohydrate; potassium hydroxide / bis-(2-hydroxy-ethyl) ether / 8 h / 200 °C
3: sulfuric acid / 18 h / Heating
4: 100 percent / methanesulfonic acid / 2 h / 90 °C
View Scheme
参考文献
Wiznycia, Alexander V.; Desper, John; Levy, Christopher J.
Dalton Transactions, 2007 , # 15 p. 1520 - 1527
参考文献
Cook; Robinson
Journal of the Chemical Society, 1938 , p. 505,511
Full Text Show Details
Fieser; Heymann
Journal of the American Chemical Society, 1941 , vol. 63, p. 2333,2339
反应条件
1: sulfuric acid / 18 h / Heating
2: 100 percent / methanesulfonic acid / 2 h / 90 °C
View Scheme
参考文献
Wiznycia, Alexander V.; Desper, John; Levy, Christopher J.
Dalton Transactions, 2007 , # 15 p. 1520 - 1527
反应条件
(i) NBS, (PhCO)2O2, (ii) aq. Na2CO3, Ag2CO3, (iii) Py*SO3, Et3N; Multistep reaction;
参考文献
Fu,P.P. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 24 p. 4265 - 4271
参考文献
Cook; Robinson
Journal of the Chemical Society, 1938 , p. 505,511
Full Text Show Details
Fieser; Heymann
Journal of the American Chemical Society, 1941 , vol. 63, p. 2333,2339
参考文献
Cook; Robinson
Journal of the Chemical Society, 1938 , p. 505,511
Full Text Show Details
Fieser; Heymann
Journal of the American Chemical Society, 1941 , vol. 63, p. 2333,2339
