N-(3-甲基丁亚基)羟胺合成路线 （共 3 条）
反应条件
1.1: t-BuOCl / CH2Cl2 2.1: EtMgBr / CH2Cl2; propan-2-ol; diethyl ether / 0 °C 2.2: propan-2-ol; CH2Cl2; diethyl ether / 0 - 20 °C 3.1: LiAlH4 / tetrahydrofuran / 0 - 20 °C 4.1: aq. K2CO3 / tetrahydrofuran / 20 °C / pH 10 5.1: 68 percent / aq. NaIO4; RuCl3 / CCl4; acetonitrile / 20 °C View Scheme
参考文献
Minter, Aaron R.; Fuller, Amelia A.; Mapp, Anna K.
Journal of the American Chemical Society, 2003 , vol. 125, # 23 p. 6846 - 6847
反应条件
1.1: t-BuOCl / CH2Cl2 2.1: EtMgBr / CH2Cl2; propan-2-ol; diethyl ether / 0 °C 2.2: propan-2-ol; CH2Cl2; diethyl ether / 0 - 20 °C 3.1: LiAlH4 / tetrahydrofuran / 0 - 20 °C 4.1: aq. K2CO3 / tetrahydrofuran / 20 °C / pH 10 5.1: 68 percent / aq. NaIO4; RuCl3 / CCl4; acetonitrile / 20 °C View Scheme
参考文献
Minter, Aaron R.; Fuller, Amelia A.; Mapp, Anna K.
Journal of the American Chemical Society, 2003 , vol. 125, # 23 p. 6846 - 6847
反应条件
1.1: t-BuOCl / CH2Cl2 2.1: EtMgBr / CH2Cl2; propan-2-ol; diethyl ether / 0 °C 2.2: propan-2-ol; CH2Cl2; diethyl ether / 0 - 20 °C 3.1: LiAlH4 / tetrahydrofuran / 0 - 20 °C 4.1: aq. K2CO3 / tetrahydrofuran / 20 °C / pH 10 5.1: 68 percent / aq. NaIO4; RuCl3 / CCl4; acetonitrile / 20 °C View Scheme
参考文献
Minter, Aaron R.; Fuller, Amelia A.; Mapp, Anna K.
Journal of the American Chemical Society, 2003 , vol. 125, # 23 p. 6846 - 6847
