1: ortho-nitrobenzoic acid With cupric(II) carbonate in various solvent(s)
T=120°C; 0.5 h;
2: 2-methoxybromobenzene With potassium fluoride; palladium acetylacetonate; iso-propyldiphenylphoshine in various solvent(s)
T=120°C; 24 h; Further stages.;
参考文献
Goossen, Lukas J.; Rodriguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M.
Journal of the American Chemical Society, 2007 , vol. 129, # 15 p. 4824 - 4833
1.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C
1.2: tetrahydrofuran; hexane / -78 - 20 °C
2.1: BCl3 / CH2Cl2 / -78 - 20 °C
3.1: pyridine / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
1.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C
1.2: tetrahydrofuran; hexane / -78 - 20 °C
2.1: BCl3 / CH2Cl2 / -78 - 20 °C
3.1: pyridine / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
1: 2-methoxybromobenzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.166667 h;
2: cyclopent-3-enecarboxylic acid methoxy-methyl-amide in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
1: 2-methoxybromobenzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.166667 h;
2: citronellic acid methoxy-methyl-amide in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
1.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C
1.2: tetrahydrofuran; hexane / -78 - 20 °C
2.1: BCl3 / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
