(S)-(+)-5-甲基-1-己醇合成路线 （共 7 条）
反应条件
lithium aluminium tetrahydride in diethyl ether Ambient temperature;
参考文献
Chattopadhay, S.; Mamdapur, V. R.; Chadha, M. S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 848 - 849
反应条件
1: With borane in tetrahydrofuran T=20°C; 5 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran T=20°C; 2 h;
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
反应条件
hydrogenchloride; dichlorobis(neomenthylindenyl)zirconium 1.) CH3CHCl2, 10 deg C, 24 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 118, # 6 p. 1577 - 1578
反应条件
1.1: Mg / diethyl ether 1.2: CuI / -50 - 20 °C 2.1: BH3 / tetrahydrofuran / 5 h / 20 °C 2.2: 2.7 g / 1 M aq. NaOH; 35 percent H2O2 / tetrahydrofuran / 2 h / 20 °C View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 75, # 1 p. 111 - 121
反应条件
1: 1.4 g / KOH / ethanol / 10 h / Heating 2: 90 percent / LiAlH4 / diethyl ether / Ambient temperature View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 28, # 1-11 p. 848 - 849
反应条件
1: dimethylformamide / 20 h / 65 °C 2: 1.4 g / KOH / ethanol / 10 h / Heating 3: 90 percent / LiAlH4 / diethyl ether / Ambient temperature View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 28, # 1-11 p. 848 - 849
参考文献
Journal of Biological Chemistry, , vol. 103, p. 305
