1-苯基-1,2-丙二酮合成路线 （共 223 条）
反应条件
titanium(III) chloride in acetic acid
0.666667 h;
参考文献
Clerici, Angelo; Porta, Ombretta
Journal of Organic Chemistry, 1991 , vol. 56, # 24 p. 6813 - 6818
参考文献
Knoll A.G.
Patent: DE614040 , 1931 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 247
参考文献
Povarnitsyna,T.N. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1977 , vol. 47, p. 1538 - 1540,1412 - 1413
反应条件
N,N'-bis(trimethylsilyl)sulfamide; boron trifluoride diethyl etherate in toluene
T=20°C; 8 h; Inert atmosphere;
参考文献
Schuettler, Christian; Li-Boehmer, Zhen; Harms, Klaus; Von Zezschwitz, Paultheo
Organic Letters, 2013 , vol. 15, # 4 p. 800 - 803
反应条件
1: water; NaOH-solution; potassium ferricyanide / man extrahiert mit Benzol, verdunstet die Bezolloesung, waescht den Rueckstand mit Aether und erwaermt ihn mit einem Gemisch von Alkohol und maessig verd. Salpetersaeure
2: zinc dust; glacial acetic acid
View Scheme
参考文献
Mueller; v. Pechmann
Chemische Berichte, 1889 , vol. 22, p. 2131
反应条件
di(cyclopentadienyl)dicarbonyltitanium(II)
1.) PhMe, RT, 2.) THF, RT, 24 h; Yield given. Multistep reaction;
参考文献
Duerr, Stefan; Hoehlein, Udo; Schobert, Rainer
Journal of Organometallic Chemistry, 1993 , vol. 458, # 1-2 p. 89 - 96
反应条件
hydrogenchloride in ethanol
0.5 h; Heating;
参考文献
Horiguchi, Emi; Matsumoto, Shinya; Funabiki, Kazumasa; Matsui, Masaki
Bulletin of the Chemical Society of Japan, 2006 , vol. 79, # 5 p. 799 - 805
反应条件
lithium aluminium tetrahydride; oxygen
T=110°C; P=759.8 Torr; 1.) oxidation, 2.) reductiv reactions of different α-diketones to different products; Product distribution;
参考文献
Rao, T. S. S.; Pritzkow, W.
Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 3 p. 474 - 482
反应条件
sodium hydroxide; sodium hypochlorite; potassium chloride in methanol
3 h; Ambient temperature;
参考文献
Guthrie, J. Peter; Cossar, John; Lu, Jinqiao
Canadian Journal of Chemistry, 1991 , vol. 69, # 12 p. 1904 - 1908
反应条件
potassium tert-butylate
Ambient temperature; Product distribution;
参考文献
Consonni, Piero; Favara, Duccio; Omodei-Sale, Amedeo; Bartolini, Giuseppe; Ricci, Alfredo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 967 - 974
