1-苯基-1,2-丙二酮合成路线 （共 223 条）
反应条件
1: 1) m-chloroperbenzoic acid / 1) CH2Cl2, reflux, 18 h, 2) 140 deg C, 1 h 2: AgBF4 / diethyl ether / 1) -50 deg C, 2) r.t., 1 h View Scheme
参考文献
Chemische Berichte, , vol. 114, # 5 p. 1858 - 1870
反应条件
in dichloromethane T=-60°C; 0.75 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 1 p. 141 - 146
反应条件
1: 1.) n-BuLi / 1.) toluene, hexane, 15 min, 2.) toluene, hexane, 3 h 2: 43 percent / KMnO4, aq. MgSO4 / toluene / 40 h / 50 - 60 °C View Scheme
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 101, # 1-4 p. 281 - 286
反应条件
1: 0.23M HCl / CHCl3 2: CH3COOH / 16 h / Heating View Scheme
参考文献
Gazzetta Chimica Italiana, , vol. 115, # 1 p. 33 - 36
反应条件
1: oxygen; sodium hydride / N,N-dimethyl-formamide / 0.2 h / 20 °C 2: hydrogenchloride; formaldehyd; water / ethanol / 0.2 h / 80 °C / Microwave irradiation View Scheme
参考文献
Synthesis, , # 18 art. no. H55411SS, p. 2984 - 2994
反应条件
1: sodium acetate / ethanol; water / 2 h 2: oxygen; sodium hydride / N,N-dimethyl-formamide / 0.2 h / 20 °C 3: hydrogenchloride; formaldehyd; water / ethanol / 0.2 h / 80 °C / Microwave irradiation View Scheme
参考文献
Synthesis, , # 18 art. no. H55411SS, p. 2984 - 2994
反应条件
water in chloroform-d1 T=20°C; 72 h; Inert atmosphereSchlenk technique;
参考文献
Organometallics, , vol. 31, # 15 p. 5494 - 5499
反应条件
silver tetrafluoroborate in diethyl ether 1) -50 deg C, 2) r.t., 1 h; Yield given. Yields of byproduct given;
参考文献
Chemische Berichte, , vol. 114, # 5 p. 1858 - 1870
反应条件
PMP in acetonitrile 4 h; Ambient temperature; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 104, # 1 p. 216 - 219
反应条件
methanol; CsSO4F 1 h; Ambient temperature; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 52, # 22 p. 5022 - 5025
