1: With water; hydrogen bromide in xylene 20 h; Heating / reflux; 2: With sodium hydroxide in water pH=12; 3: With hydrogenchloride; bis(trichloromethyl) carbonate; carbon Product distribution / selectivity; more than 3 stages;
参考文献
DSM IP ASSETS B.V.; FUDAN UNIVERSITY
Patent: WO2009/49476 A1, 2009 ;
Location in patent: Page/Page column 38-39 ;
1: With water; hydrogen bromide in xylene 20 h; Heating / reflux; 2: With sodium hydroxide in water pH=12; 3: With hydrogenchloride; bis(trichloromethyl) carbonate; carbon Product distribution / selectivity; more than 3 stages;
参考文献
DSM IP ASSETS B.V.; FUDAN UNIVERSITY
Patent: WO2009/49476 A1, 2009 ;
Location in patent: Page/Page column 39-40 ;
1: With water; hydrogen bromide in xylene 20 h; Heating / reflux; 2: With sodium hydroxide in water pH=12; 3: With hydrogenchloride; bis(trichloromethyl) carbonate; carbon Product distribution / selectivity; more than 3 stages;
参考文献
DSM IP ASSETS B.V.; FUDAN UNIVERSITY
Patent: WO2009/49476 A1, 2009 ;
Location in patent: Page/Page column 39 ;
1: With water; hydrogen bromide in xylene 24 h; Heating / reflux; 2: With sodium hydroxide in water pH=12; 3: With hydrogenchloride; trichloromethyl chloroformate; carbon Product distribution / selectivity; more than 3 stages;
参考文献
DSM IP ASSETS B.V.; FUDAN UNIVERSITY
Patent: WO2009/49476 A1, 2009 ;
Location in patent: Page/Page column 38 ;
1: With hydrogen bromide in water T=125 - 126°C; 8 h; 2: With bis(trichloromethyl) carbonate; water; sodium hydroxide in toluene T=20°C; pH=8 - 9; 1 h; 3: With hydrogenchloride in water; toluene
Baggiolini, Enrico G.; Lee, Hsi Lin; Pizzolato, Giacomo; Uskokovic, Milan R.
Journal of the American Chemical Society, 1982 , vol. 104, # 23 p. 6460 - 6462
