4-溴-4',4''-二甲基三苯胺合成路线 （共 5 条）
反应条件
N-bromosuccinmide in N,N-dimethyl-formamide T=20°C;
参考文献
NATIONAL INSTITUTE FOR MATERIALS SCIENCE; Saint Gobain Glass France; ASHRAFUL, Islam; HATA, Kawae; HAN, Liyuan
Patent: WO2013/8951 A1, 2013 ;
Location in patent: Page/Page column 31 ;
反应条件
potassium hydroxide; 1,10-phenanthroline; copper(l) chloride in toluene T=125°C; Ullmann condensation; 5 h;
参考文献
Goodbrand, H. Bruce; Hu, Nan-Xing
Journal of Organic Chemistry, 1999 , vol. 64, # 2 p. 670 - 674
反应条件
1,1'-bis(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate in toluene T=90°C; Buchwald-Hartwig coupling; 15 h; Inert atmosphere;
参考文献
Chang, Yuan Jay; Chow, Tahsin J.
Tetrahedron, 2009 , vol. 65, # 46 p. 9626 - 9632
反应条件
potassium hydroxide; 1,10-phenanthroline; copper(l) chloride in o-xylene T=145°C; 1 h;
参考文献
Anemian; Cupertino; Mackie; Yeates
Tetrahedron Letters, 2005 , vol. 46, # 39 p. 6717 - 6721
反应条件
1: With manganese; [2,2']bipyridinyl; (Z,Z)-1,5-cyclooctadiene; niobium bromide in N,N-dimethyl-formamide; toluene T=20°C; Yamamoto coupling; 2: N-(4-bromophenyl)-4-methyl-N-(p-tolyl)benzenamine in N,N-dimethyl-formamide; toluene T=50°C; 48 h;
参考文献
US2006/58524 A1, ;
Page/Page column 7-9 ;
