9-丁基-9H-芴-9-醇合成路线 （共 14 条）
反应条件
triethylsilane; boron trifluoride diethyl etherate in dichloromethane T=0 - 20°C; 48 h; Inert atmosphereSchlenk technique;
参考文献
Li, Hui; Aquino, Adelia J. A.; Cordes, David B.; Hung-Low, Fernando; Hase, William L.; Krempner, Clemens
Journal of the American Chemical Society, 2013 , vol. 135, # 43 p. 16066 - 16069
反应条件
1: in tetrahydrofuran; hexane
T=0°C; 1 h; Inert atmosphere;
2: With sodium carbonate in tetrahydrofuran; hexane; water
pH=12; Inert atmosphere;
3: With hydrogenchloride in water
pH=1; Inert atmosphere;
参考文献
Tilly, David; Fu, Jian-Min; Zhao, Bao-Ping; Alessi, Manlio; Castanet, Anne-Sophie; Snieckus, Victor; Mortier, Jacques
Organic Letters, 2010 , vol. 12, # 1 p. 68 - 71
反应条件
oxygen; N-benzyl-trimethylammonium hydroxide
T=25°C; Oxidation;
参考文献
Sprinzak
Journal of the American Chemical Society, 1958 , vol. 80, p. 5449,5452
参考文献
Allelix Neuroscience Inc.
Patent: US6162824 A1, 2000 ;
反应条件
in N,N-dimethyl-formamide
Yields of byproduct given;
参考文献
Lund, Torben; Pedersen, Morten L.; Frandsen, Lars A.
Tetrahedron Letters, 1994 , vol. 35, # 49 p. 9225 - 9226
反应条件
1-pentynyl-copper
1) Ether, 2) -20 deg C, 1 h.; Yield given. Multistep reaction;
参考文献
Sokolov, G. P.; Korits, V. R.; Freimanis, Ya. F.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 3 p. 622 - 627
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 3 p. 683 - 690
反应条件
in tetrahydrofuran
Yield given. Yields of byproduct given;
参考文献
Lund, Torben; Pedersen, Morten L.; Frandsen, Lars A.
Tetrahedron Letters, 1994 , vol. 35, # 49 p. 9225 - 9226
反应条件
(i) Mg, ether, (ii) CdBr2, (iii) /BRN= 1636531/; Multistep reaction;
参考文献
Gocmen,M. et al.
Bulletin de la Societe Chimique de France, 1973 , p. 562 - 569
反应条件
copper(l) iodide
1) Ether, -40 deg C, 15 min, 2) 2 h; Yield given. Multistep reaction;
参考文献
Sokolov, G. P.; Korits, V. R.; Freimanis, Ya. F.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 3 p. 622 - 627
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 3 p. 683 - 690
反应条件
1-pentynyl-copper; N,N,N',N',N'',N''-hexamethylphosphoric triamide
1) Ether, hexane, 1 h, 3) -20 deg C, 1 h.; Yield given. Multistep reaction;
参考文献
Sokolov, G. P.; Korits, V. R.; Freimanis, Ya. F.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 3 p. 622 - 627
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 3 p. 683 - 690
