(2,4,6-三甲基苯基)-锂合成路线 （共 30 条）
反应条件
in hexane under N2 or Ar; dropwise addn. of a suspn. of mesityllithium in hexane to GaCl3 in hexane at -63°C under stirring, stirred for 1 h at -63°C and for 14 h at room temp.; volatiles were removed under reduced pressure, distilled at 150°Cand 4.0E-3 Torr;
参考文献
Yamaguchi, Takeshi; Ueno, Keiji; Ogino, Hiroshi
Organometallics, 2001 , vol. 20, # 3 p. 501 - 507
参考文献
Oehme, H.; Weiss, H.
Journal of Organometallic Chemistry, 1987 , vol. 319, p. C16 - C18
参考文献
Rosenberg
Journal of the American Chemical Society, 1954 , vol. 76, p. 4389
反应条件
Yield given. Multistep reaction;
参考文献
Zadel, Guido; Breitmaier, Eberhard
Angewandte Chemie, 1992 , vol. 104, # 8 p. 1070 - 1071
反应条件
2: SOCl2 3: Zn, AcOH View Scheme
参考文献
Chandross,E.A.; Sheley,C.F.
Journal of the American Chemical Society, 1968 , vol. 90, # 16 p. 4345 - 4354
反应条件
titanium(IV) isopropylate; tert.-butylhydroperoxide in diethyl ether T=-78°C; 12 h;
参考文献
Moeller, Michael; Husemann, Marc; Boche, Gernot
Journal of Organometallic Chemistry, 2001 , vol. 624, # 1-2 p. 47 - 52
反应条件
in tetrahydrofuran T=-50°C; Carbonylation; P=759.811 Torr;
参考文献
Journal of Chemical Research - Part S, , # 7 p. 422 - 423
反应条件
in tetrahydrofuran T=-100°C;
参考文献
Journal of Organic Chemistry, , vol. 58, # 21 p. 5843 - 5845
反应条件
1: carbon monoxide; mesityllithium in tetrahydrofuran T=-78°C; Carbonylation; P=759.811 Torr; 2: acetic anhydride in tetrahydrofuran Acylation;
参考文献
Nudelman, Norma; Schulz, Hernan
Journal of Chemical Research - Part S, 1999 , # 7 p. 422 - 423
反应条件
1: carbon monoxide; mesityllithium in tetrahydrofuran T=45°C; Carbonylation; P=759.811 Torr; 2: acetic anhydride in tetrahydrofuran Acylation;
参考文献
Nudelman, Norma; Schulz, Hernan
Journal of Chemical Research - Part S, 1999 , # 7 p. 422 - 423
