(2,4,6-三甲基苯基)-锂合成路线 （共 30 条）
反应条件
in tetrahydrofuran to suspn. of HgCl2 in THF added mesityllithium at room temp.; stirred for 10 h; volatiles removed in vacuo; residue extd. with benzene; extract filteredthrough frit; filtrate slowly concd.;
参考文献
Hayashi, Mari; Bolte, Michael; Wagner, Matthias; Lerner, Hans-Wolfram
Zeitschrift fur Anorganische und Allgemeine Chemie, 2011 , vol. 637, # 6 p. 646 - 649
反应条件
1: tetrahydrofuran 2: tetrahydrofuran View Scheme
参考文献
Kawashima, Takayuki; Yamashita, Naoko; Okazaki, Renji
Journal of the American Chemical Society, 1995 , vol. 117, # 22 p. 6142 - 6143
反应条件
phosphorus trichoride in diethyl ether T=0 - 25°C; 15 h;
参考文献
Journal of Organometallic Chemistry, , vol. 310, p. 21 - 26
反应条件
in tetrahydrofuran addn. of B-compd. to org. compd. in THF, stirring (-78°C, 1.5 h); addn. of satd. soln. of aq. NH4Cl (-78°C), warming (room temp.),DDN: OF H2O, shaking with ether, washing of ether extracts (satd. aq. NaHCO3 and satd. brine), drying (Na2SO4), filtration, evapn. (vac.), crystn. (H2O);
参考文献
Morgan, Jacqueline; Pinhey, John T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 715 - 720
反应条件
1: diethyl ether; pentane 2: HF / benzene View Scheme
参考文献
Ranaivonjatovo, Henri; Escudie, Jean; Couret, Claude; Satge, Jacques
New Journal of Chemistry, 1989 , vol. 13, p. 389 - 398
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether addn. of soln. of BrSiCl3 in THF to soln. of org.compd. in THF (-78°C), stirring (2 h, -78°C), addn. of HCl in ether; not isolated; (1)H-NMR spectrometry;
参考文献
Weiss, H.; Oehme, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 572, p. 186 - 191
反应条件
tetrachlorosilane in diethyl ether 5 h; Ambient temperature;
参考文献
Ishikawa, Mitsuo; Katayama, Seiji; Kumada, Makoto
Journal of Organometallic Chemistry, 1983 , vol. 248, # 3 p. 251 - 260
反应条件
in benzene To a benzene soln. of complex was added a soln. of slightly excess LiBr or MesLi in ether;; not sepd., detected by UV-spectroscopy;;
参考文献
Tobita, Hiromi; Habazaki, Hiroki; Ogino, Hiroshi
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 2 p. 797 - 799
参考文献
Danopoulos, Andreas A.; Wilkinson, Geoffrey; Hussain-Bates, Bilquis; Hursthouse, Michael B.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1992 , # 22 p. 3165 - 3170
反应条件
in benzene To a benzene soln. of complex was added a soln. of slightly excess LiBr or MesLi in ether;; not sepd., detected by UV-spectroscopy;;
参考文献
Tobita, Hiromi; Habazaki, Hiroki; Ogino, Hiroshi
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 2 p. 797 - 799
