(2,4,6-三甲基苯基)-锂合成路线 （共 30 条）
反应条件
in benzene To a benzene soln. of complex was added a soln. of slightly excess LiBr or MesLi in ether;; not sepd., detected by UV-spectroscopy;;
参考文献
Tobita, Hiromi; Habazaki, Hiroki; Ogino, Hiroshi
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 2 p. 797 - 799
反应条件
tert.-butyl lithium in diethyl ether; pentane
T=-78 - 20°C; 0.666667 h;
参考文献
Vedejs, Edwin; Lee, Namkyu
Journal of the American Chemical Society, 1995 , vol. 117, # 3 p. 891 - 899
反应条件
TeCl4 in diethyl ether
参考文献
Laur, Peter H.; Saberi-Niaki, Seyedeh M.; Scheiter, Michael; Hu, Chunhua; Englert, Ulli; Wang, Yuekui; Fleischhauer, Joerg
Phosphorus, Sulfur and Silicon and the Related Elements, 2005 , vol. 180, # 3-4 p. 1035 - 1044
反应条件
1: 55 percent / SiHCl3 / toluene / 1.) from -70 deg C to RT, 2.) 100 deg C, 8 h
2: 82 percent / Na, K / toluene / 8 h / Heating
View Scheme
参考文献
Weidenbruch, M.; Schaefer, A.; Rankers, R.
Journal of Organometallic Chemistry, 1980 , vol. 195, # 2 p. 171 - 184
反应条件
(i), (ii) MeSO3H; Multistep reaction;
参考文献
Ramsey,B.G.; O'Neill,S.J.
Journal of Organometallic Chemistry, 1977 , vol. 141, p. 257 - 273
反应条件
diethyl ether
Erhitzen des Reaktionsprodukts mit Nitrobenzol;
参考文献
Oldham; Johns
Journal of the American Chemical Society, 1939 , vol. 61, p. 3289
反应条件
1: pentane; diethyl ether / -78 °C
View Scheme
参考文献
Harloff, Joerg; Popowski, Eckhard; Reinke, Helmut
Journal of Organometallic Chemistry, 2007 , vol. 692, # 7 p. 1421 - 1441
反应条件
trichlorosilane in toluene
1.) from -70 deg C to RT, 2.) 100 deg C, 8 h;
参考文献
Weidenbruch, M.; Schaefer, A.; Rankers, R.
Journal of Organometallic Chemistry, 1980 , vol. 195, # 2 p. 171 - 184
反应条件
diethyl ether; acetone
参考文献
Brown; Grayson
Journal of the American Chemical Society, 1953 , vol. 75, p. 20,23
反应条件
[VO(OEt)Cl2]
1.) Et2O, RT, 1 h, 2.) Et2O, reflux, 2 h; Yield given. Multistep reaction;
参考文献
Ishikawa; Ogawa; Hirao
Journal of the American Chemical Society, 1998 , vol. 120, # 20 p. 5124 - 5125
