1.1: 83 percent / DIAD; Ph3P / benzene / 1 h / 20 °C 2.1: KOH / methanol / 0.17 h / 0 °C 2.2: 85 percent / methanol / 1 h / 0 °C 3.1: 92 percent / oxone / methanol; H2O / 0 °C 4.1: 82 percent / KOH; Al2O3; CBr2F2 / CH2Cl2 / 1 h / 20 °C View Scheme

暂无反应条件数据

1: 86 percent / Et3N / CH2Cl2 / 0.5 h / -10 - 0 °C 2: 59 percent / benzene; dimethylformamide / 16 h / Heating 3: 84 percent / H2O, NaCl / dimethylsulfoxide / 3 h / 160 - 165 °C 4: 77 percent / LiAlH4, EtOH / diethyl ether / 0.5 h / 0 - 5 °C 5: 78 percent / pyridinium chlorochromate / CH2Cl2 / 4 h / 10 °C 6: 1.) NaH / 1.) 1,2-dimethoxyethane, 20 deg C, 2.) 1,2-dimethoxyethane, 10 deg C, 4 h, 60 deg C, 1 h View Scheme

1: H2 / Pd/C 2: PCC View Scheme

暂无反应条件数据

1.1: 83 percent / DIAD; Ph3P / benzene / 1 h / 20 °C 2.1: KOH / methanol / 0.17 h / 0 °C 2.2: 68 percent / methanol / 1 h / 0 °C 3.1: 90 percent / oxone / methanol; H2O / 0 °C 4.1: 85 percent / KOH; Al2O3; CBr2F2 / CH2Cl2 / 1 h / 20 °C View Scheme

manganese(IV) oxide in dichloromethane T=20°C; 24 h;

sodium carbonate in tetrahydrofuran 0.5 h; Ambient temperature;

hydrogen; palladium on activated charcoal

4-(N,N-dimethlyamino)pyridine; dicyclohexyl-carbodiimide in dichloromethane 2 h; Ambient temperature;