1: 4-(pyridin-3-yl)pyrimidin-2-ylamine With C43H62NO2PPd; sodium t-butanolate in 1,4-dioxane; tert-butyl alcohol 0.166667 h; Sonication; 2: N-(3-bromo-4-methylphenyl)-4-((4-methylpiperazin-1-yl)methyl)benzamide With 1,8-diazabicyclo[5.4.0]undec-7-ene in 1,4-dioxane; tert-butyl alcohol T=150°C; 0.5 h;