(1S,3S)-2,2,3-三甲基环戊烷羧酸合成路线 (共 9 条)
反应条件
chromium(VI) oxide; sulfuric acid in water; acetone
T=20°C; 0.5 h;
参考文献
Ruedi, Georg; Nagel, Matthias; Hansen, Hans-Jurgen
Organic Letters, 2003 , vol. 5, # 15 p. 2691 - 2693
反应条件
1.1: 73 percent / 630 °C / 0.02 - 0.03 Torr
2.1: H2SO4; HNO3 / -15 °C
2.2: 78 percent / H2SO4 / 0.25 h / 0 °C
3.1: 3-chlorobenzenecarboperoxoic acid (MCPBA); trifluoroacetic acid (TFA) / CH2Cl2 / 20 °C
4.1: LiOH / methanol; H2O / 20 °C
5.1: 99 percent / CrO3; H2SO4 / H2O; acetone / 30 h / 0 - 20 °C
View Scheme
参考文献
Rueedi, Georg; Hansen, Hans-Juergen
Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989
反应条件
1.1: H2SO4; HNO3 / -15 °C
1.2: 78 percent / H2SO4 / 0.25 h / 0 °C
2.1: 3-chlorobenzenecarboperoxoic acid (MCPBA); trifluoroacetic acid (TFA) / CH2Cl2 / 20 °C
3.1: LiOH / methanol; H2O / 20 °C
4.1: 99 percent / CrO3; H2SO4 / H2O; acetone / 30 h / 0 - 20 °C
View Scheme
参考文献
Rueedi, Georg; Hansen, Hans-Juergen
Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989
反应条件
1: 89 percent / 3-chlorobenzenecarboperoxoic acid (MCPBA); trifluoroacetic acid (TFA) / CH2Cl2 / 240 h / 20 °C
2: 98 percent / LiOH / methanol; H2O / 0.5 h / 20 °C
3: 99 percent / CrO3; H2SO4 / H2O; acetone / 30 h / 0 - 20 °C
View Scheme
参考文献
Rueedi, Georg; Hansen, Hans-Juergen
Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989
反应条件
1: 98 percent / LiOH / methanol; H2O / 0.5 h / 20 °C
2: 99 percent / CrO3; H2SO4 / H2O; acetone / 30 h / 0 - 20 °C
View Scheme
参考文献
Rueedi, Georg; Hansen, Hans-Juergen
Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989
反应条件
1.1: m-chloroperbenzoic acid; trifluoroacetic acid / CH2Cl2
1.2: Alkaline hydrolysis
2.1: 100 percent / CrO3; H2SO4 / acetone; H2O / 0.5 h / 20 °C
View Scheme
参考文献
Ruedi, Georg; Nagel, Matthias; Hansen, Hans-Jurgen
Organic Letters, 2003 , vol. 5, # 15 p. 2691 - 2693
反应条件
1.1: 45 percent / 620 °C
2.1: m-chloroperbenzoic acid; trifluoroacetic acid / CH2Cl2
2.2: Alkaline hydrolysis
3.1: 100 percent / CrO3; H2SO4 / acetone; H2O / 0.5 h / 20 °C
View Scheme
参考文献
Ruedi, Georg; Nagel, Matthias; Hansen, Hans-Jurgen
Organic Letters, 2003 , vol. 5, # 15 p. 2691 - 2693
反应条件
1.1: 95 percent / CeCl3 / tetrahydrofuran / 0.5 h / 20 °C
2.1: 73 percent / 630 °C / 0.02 - 0.03 Torr
3.1: H2SO4; HNO3 / -15 °C
3.2: 78 percent / H2SO4 / 0.25 h / 0 °C
4.1: 3-chlorobenzenecarboperoxoic acid (MCPBA); trifluoroacetic acid (TFA) / CH2Cl2 / 20 °C
5.1: LiOH / methanol; H2O / 20 °C
6.1: 99 percent / CrO3; H2SO4 / H2O; acetone / 30 h / 0 - 20 °C
View Scheme
参考文献
Rueedi, Georg; Hansen, Hans-Juergen
Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989
反应条件
1: 3-chlorobenzenecarboperoxoic acid (MCPBA); trifluoroacetic acid (TFA) / CH2Cl2 / 20 °C
2: LiOH / methanol; H2O / 20 °C
3: 99 percent / CrO3; H2SO4 / H2O; acetone / 30 h / 0 - 20 °C
View Scheme
参考文献
Rueedi, Georg; Hansen, Hans-Juergen
Helvetica Chimica Acta, 2004 , vol. 87, # 8 p. 1968 - 1989