2-乙酰基萘-1,4-二酮合成路线 （共 54 条）
反应条件
in benzene
byproducts: 5-acetyl-2H-benzo{h}chromene-6-ol; dissolved acylquinone and allylstannane stood for 20 h under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); 5-acetyl-2H-benzo(h)chromene-6-ol was obtained with a yield of 2percent; NMR; IR; mass spectra; UV/VIS; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in acetonitrile
dissolved acylquinone and allylstannane stood for 1 h under Ar; concentrated; column chromy. (silica gel); eluted (hexane/ether); 3a-acetyl-2-trimethylstannyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta(b)naphthalene-4,9-dione was not obtained; NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in acetonitrile
dissolved acylquinone and allylstannane stood for 1 h under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in benzene
21 h; with further acylquinones and allylstannanes also, various solvents, reaction time; Product distributionMechanism;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
