1: With n-butyllithium; 2-(dimethylamino)-ethanol in hexane
T=0°C; 1 h;
2: With carbon tetrabromide in tetrahydrofuran; hexane
T=-78°C; 1 h; Further stages.;
参考文献
Kaminski, Thomas; Gros, Philippe; Fort, Yves
European Journal of Organic Chemistry, 2003 , # 19 p. 3855 - 3860
Clarke, Kenneth; Goulding, John; Scrowston, Richard M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1501 - 1505
1: 1.) chromium trioxide, sulphuric acid / 1.) 70 deg C, 2.) reflux, 2 h
2: hydrogen peroxide / acetic acid / 3.5 h / 100 °C
View Scheme
参考文献
Clarke, Kenneth; Goulding, John; Scrowston, Richard M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1501 - 1505