1-溴-2,4-二硝基苯合成路线 (共 145 条)
反应条件
oxygen in N,N-dimethyl-formamide
T=22 - 23°C; 2016 h; other temperatures, order of reaction, energy of activation in the presence of H2O18; Thermodynamic dataKineticsProduct distribution;
参考文献
Ivanova, T.M.; Shein, S.M.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 891 - 897
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 5 p. 891 - 897
反应条件
sodium azide; (C16H33)Bu3P(1+)*N3(1-) in water; chlorobenzene
T=25°C;
参考文献
Landini, Dario; Maia, Angelamaria; Montanari, Fernando
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 461 - 466
反应条件
2: chromic acid; acetic acid
View Scheme
参考文献
Cook
Journal of the American Chemical Society, 1910 , vol. 32, p. 1291
反应条件
1: alcohol; sodium ethylate
2: tin dichloride; hydrochloric acid; alcohol
3: concentrated hydrochloric acid / 130 °C
View Scheme
参考文献
Reissert; Heller
Chemische Berichte, 1904 , vol. 37, p. 4369
反应条件
1: alcohol; hydrazine hydrate
2: alcohol; sulfuric acid
View Scheme
参考文献
Curtius; Dedichen
Journal fuer Praktische Chemie (Leipzig), 1894 , vol. <2> 50, p. 254
Journal fuer Praktische Chemie (Leipzig), 1895 , vol. <2> 52, p. 272
反应条件
copper; bis(dibenzylideneacetone)-palladium(0) in dimethyl sulfoxide
T=70°C; Ullmann cross-coupling; 1 h;
参考文献
Banwell, Martin G.; Kelly, Brian D.; Kokas, Okanya J.; Lupton, David W.
Organic Letters, 2003 , vol. 5, # 14 p. 2497 - 2500
反应条件
lithium alcoholate of 5-hydroxymethyl-3-methyl-5-nitro-1,3-tetrahydrooxazine in dimethyl sulfoxide
参考文献
Galeeva, A. G.; Trifonova, V. N.; Kasatkina, A. A.; Zorin, V. V.; Rakhmankulov, D. L.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 6.2 p. 1019 - 1021
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 6 p. 1228 - 1230
参考文献
Forrest,J.
Journal of the Chemical Society, 1960 , p. 594 - 601
反应条件
copper; nitrobenzene
参考文献
Ullmann; Bielecki
Chemische Berichte, 1901 , vol. 34, p. 2176
反应条件
in benzene
T=60°C; Title compound not separated from byproducts;
参考文献
Nudelman, N. Sbarbati; Socolovsky, S. E.
Tetrahedron Letters, 1980 , vol. 21, p. 3331 - 3334