1-(4-甲基苯基)乙胺合成路线 （共 16 条）
反应条件
1: With [((R)-tol-binap)RuCl2(DMF)x]; ammonia; ammonium formate in methanol T=85°C; Leuckart-Wallach reaction; 21 h; 2: With hydrogenchloride in ethanol 1 h; Heating; Title compound not separated from byproducts;
参考文献
Angewandte Chemie - International Edition, , vol. 42, # 44 p. 5472 - 5474
反应条件
hexacarbonyl molybdenum in water; acetonitrile T=85°C; 1 h;
参考文献
Atobe, Masakazu; Yamazaki, Naoki; Kibayashi, Chihiro
Journal of Organic Chemistry, 2004 , vol. 69, # 17 p. 5595 - 5607
反应条件
6-(1,2:3,4-di-O-isopropylidene-α-D-galactopyranosyl) hydrogen phthalate in isopropyl alcohol Heating;
参考文献
Mereyala, Hari Babu; Fatima, Liyakat; Pola, Pallavi
Tetrahedron Asymmetry, 2004 , vol. 15, # 4 p. 585 - 587
反应条件
Ni T=110°C; 2 h; Inert atmosphere;
参考文献
Geukens, Inge; Plessers, Eva; Seo, Jin Won; De Vos, Dirk E.
European Journal of Inorganic Chemistry, 2013 , # 14 p. 2623 - 2628
反应条件
borane-THF; C19H23BNO3(1-)*H(1+) in tetrahydrofuran; 1,4-dioxane T=0°C; Inert atmosphere; enantioselective reaction;
参考文献
Ou, Wenhua; Espinosa, Sandraliz; Melendez, Hector J.; Farre, Silvia M.; Alvarez, Jaime L.; Torres, Valerie; Martinez, Ileanne; Santiago, Kiara M.; Ortiz-Marciales, Margarita
Journal of Organic Chemistry, 2013 , vol. 78, # 11 p. 5314 - 5327
反应条件
D-(+)-camphoric acid
参考文献
Journal of the American Chemical Society, , vol. 54, p. 4712,4714
反应条件
1: With (Ph)2SiH2; silver trifluoromethanesulfonate in ethylene glycol dimethyl ether T=20°C; 40 h; 2: With hydrogenchloride in methanol; ethylene glycol dimethyl ether Further stages. Title compound not separated from byproducts.;
参考文献
Chemical Communications, , # 22 p. 2360 - 2361
反应条件
2,6-dimethylpyridine; chiral 1-azaspiro[5.5]undecane N-oxyl radical; sodium perchlorate in water; acetonitrile Oxidation; 5 h; Electrolysis;
参考文献
Chemical Communications, , # 19 p. 1983 - 1984
反应条件
1.1: bromine / dichloromethane / 1 h / 0 °C 2.1: hydroxylamine hydrochloride / water; methanol / 25 °C 3.1: sodium tetrahydroborate / water; acetonitrile / 0.17 h / 25 °C 4.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 0 °C 4.2: 18 h / 20 °C 5.1: C19H23BNO3(1-)*H(1+); borane-THF / 1,4-dioxane; tetrahydrofuran / 0 °C / |Inert atmosphere View Scheme
参考文献
Journal of Organic Chemistry, , vol. 78, # 11 p. 5314 - 5327
反应条件
1: toluene; diethyl ether / 0.42 h / -20 °C 2: 91 percent / Mo(CO)6 / acetonitrile; H2O / 1 h / 85 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 69, # 17 p. 5595 - 5607
