1-(4-甲基苯基)乙胺合成路线 （共 16 条）
反应条件
1: ethanol; sodium 2: (1R)-cis-camphoric acid View Scheme
参考文献
Journal of the American Chemical Society, , vol. 54, p. 4712,4714
反应条件
hydrogen; Pd-BaSO4 in toluene T=70°C; P=75.0075 Torr; 24 h; Kinetics;
参考文献
Chemistry - A European Journal, , vol. 13, # 7 p. 2034 - 2043
反应条件
hexacarbonyl molybdenum in water; acetonitrile Heating;
参考文献
Tetrahedron Letters, , vol. 42, # 30 p. 5029 - 5032
反应条件
1: 1.) THF, ether, r.t., 30 min, 2.) 30 min 2: DIBAL, ZnBr2 / tetrahydrofuran; hexane / Ambient temperature 3: 87 percent / TFA / methanol View Scheme
参考文献
Journal of the Chemical Society - Perkin Transactions 1, , # 7 p. 691 - 703
反应条件
1.1: hydroxylamine hydrochloride / water; methanol / 25 °C 2.1: sodium tetrahydroborate / water; acetonitrile / 0.17 h / 25 °C 3.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 0 °C 3.2: 18 h / 20 °C 4.1: C19H23BNO3(1-)*H(1+); borane-THF / 1,4-dioxane; tetrahydrofuran / 0 °C / |Inert atmosphere View Scheme
参考文献
Journal of Organic Chemistry, , vol. 78, # 11 p. 5314 - 5327
反应条件
1.1: sodium tetrahydroborate / water; acetonitrile / 0.17 h / 25 °C 2.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 0 °C 2.2: 18 h / 20 °C 3.1: C19H23BNO3(1-)*H(1+); borane-THF / 1,4-dioxane; tetrahydrofuran / 0 °C / |Inert atmosphere View Scheme
参考文献
Journal of Organic Chemistry, , vol. 78, # 11 p. 5314 - 5327
