hydrogenchloride; titanium(III) chloride; aluminium in ethanol T=20°C; pinacol coupling; 0.666667 h; sonication; Title compound not separated from byproducts;
1: triethylaluminum With titanium(IV) isopropylate; (S)-2-hydroxy-3-phenylpropionic acid in tetrahydrofuran; toluene T=20°C; 6 h; 2: 3-chloro-benzaldehyde in tetrahydrofuran; toluene T=20°C; 6 h; Title compound not separated from byproducts;
sodium citrate buffer pH 6.0; thiamine diphosphate; magnesium sulfate T=30°C; 23 h; recombinant Zymomonas mobilis pyruvate decarboxylase; Title compound not separated from byproducts;
参考文献
Bornemann, Stephen; Crout, David H. G.; Dalton, Howard; Kren, Vladimir; Lobell, Mario; Dean, Gregory; Thomson, Nicholas; Turner, Margaret M.
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 5 p. 425 - 430
1: diethylzinc; phenylacetylene With chiral bicyclo[3.2.1]octane-based alcohol in tetrahydrofuran; hexane 1 h; 2: 3-chloro-benzaldehyde in tetrahydrofuran; hexane T=0°C; 6 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Scarpi, Dina; Galbo, Fabrizio Lo; Guarna, Antonio
Tetrahedron Asymmetry, 2006 , vol. 17, # 9 p. 1409 - 1414
