1: pentafluorophenyl chloride With n-butyllithium in diethyl ether; hexane T=-78°C; 1 h; 2: 1-methyl-pyrrole in diethyl ether; hexane T=-78 - 20°C; Diels-Alder reaction; Further stages.;

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3-chloro-benzenecarboperoxoic acid in chloroform 24 h; Ambient temperature;

3,6-bis(2-pyridinyl)-1,2,4,5-tetrazine in chloroform 4 h; Heating;