4-苯基-3-丁炔-2-醇合成路线 （共 25 条）
反应条件
NB-Enantride in tetrahydrofuran; diethyl ether; pentane T=-100°C; 3 h;
参考文献
Journal of Organic Chemistry, , vol. 47, # 12 p. 2495 - 2496
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran T=-78 - 20°C; 2 h;
参考文献
Synthesis, , # 11 p. 1741 - 1750
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine T=20°C; Sonogashira coupling; 5 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 13, # 19 p. 5314 - 5317
反应条件
1: 3-pyrrol-1-yl-propionic acid 1-methyl-prop-2-ynyl ester in acetonitrile Electrochemical reaction; 2: iodobenzene With copper(l) iodide; triethylamine; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide T=20°C; Sonogashira reaction; 12 h; 3: With sodium methylate in tetrahydrofuran; methanol T=20°C; 1 h;
参考文献
Synlett, , # 14 p. 2513 - 2516
反应条件
1: (S)-1-ethyl-2-(p-tolylsulfinyl)benzene With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane T=-78 - 0°C; Cooling; 2: With copper (I) cyanide; lithium chloride in tetrahydrofuran; hexane T=-78°C; 0.0833333 h; Cooling; 3: 4-phenylbut-3-yn-2-yl methanesulfonate in tetrahydrofuran; hexane T=-78°C; 0.0833333 h; optical yield given as percent de;
参考文献
Angewandte Chemie - International Edition, , vol. 47, # 36 p. 6836 - 6839
反应条件
in diethyl ether T=20°C; Meyer-Schuster Rearrangement; 1 h; Inert atmosphere;
参考文献
Tetrahedron Letters, , vol. 54, # 6 p. 459 - 461
反应条件
sodium nitrite in ethanol 48 h; Ambient temperature;
参考文献
Journal of Organic Chemistry, , vol. 53, # 12 p. 2870 - 2872
反应条件
sodium nitrite in N,N-dimethyl-formamide
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 16, p. 1148 - 1150
Zhurnal Organicheskoi Khimii, , vol. 16, # 6 p. 1328 - 1330
反应条件
titanium(IV) isopropylate; 2,2'-azo-bisisobutyronitrile; tetranaphthyl-TADDOL; Ph2SbH in hexane 16 h; Heating;
参考文献
Journal of Organometallic Chemistry, , vol. 571, # 2 p. 297 - 303
参考文献
Advanced Synthesis and Catalysis, , vol. 351, # 11-12 p. 1955 - 1960
