(R)-(-)-6-甲基-5-烯基-2-戊醇合成路线 （共 50 条）
反应条件
2: pyridine 3: LiAlH4 / tetrahydrofuran View Scheme
参考文献
Chemistry Letters, , p. 1913 - 1914
反应条件
1: pyridine 2: LiAlH4 / tetrahydrofuran View Scheme
参考文献
Chemistry Letters, , p. 1913 - 1914
参考文献
Takano, Seiichi; Yanase, Masashi; Takahashi, Michiyasu; Ogasawara, Kunio
Chemistry Letters, 1987 , p. 2017 - 2020
反应条件
Lipase PS; tert-butyl methyl ether T=30°C; Esterification; 20 h; Enzymatic reaction; Title compound not separated from byproducts.;
参考文献
Journal of Organic Chemistry, , vol. 65, # 1 p. 83 - 88
反应条件
1: 1.) 1,8-diazabicyclo<5.5.0>undec-7-ene (DBU) / 1.) THF, from 0 deg C to RT, 1 h, 2.) THF, RT, 6 h 2: 83 percent / pyridinium chlorochromate (PCC) / CH2Cl2 / 1.5 h / Ambient temperature 3: 58 percent / tributyltin hydride (TBTH), 2,2'-azobisisobutyronitrile (AIBN) / toluene / 0.83 h / 110 °C 4: 72 percent / D-glucose, 1 M NaOH / H2O / 72 h / Ambient temperature; baker's yeast View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 32, # 6 p. 615 - 617
反应条件
1: 83 percent / pyridinium chlorochromate (PCC) / CH2Cl2 / 1.5 h / Ambient temperature 2: 58 percent / tributyltin hydride (TBTH), 2,2'-azobisisobutyronitrile (AIBN) / toluene / 0.83 h / 110 °C 3: 72 percent / D-glucose, 1 M NaOH / H2O / 72 h / Ambient temperature; baker's yeast View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 32, # 6 p. 615 - 617
反应条件
1: 58 percent / tributyltin hydride (TBTH), 2,2'-azobisisobutyronitrile (AIBN) / toluene / 0.83 h / 110 °C 2: 72 percent / D-glucose, 1 M NaOH / H2O / 72 h / Ambient temperature; baker's yeast View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 32, # 6 p. 615 - 617
反应条件
Tris-HCl buffer; lipase PPS T=30°C; var. conc. of reagents, also in the presence of various organic solventsand detergents; Rate constant;
参考文献
Tetrahedron, , vol. 52, # 15 p. 5397 - 5406
反应条件
1: pyridine 3: NaOH View Scheme
参考文献
Tetrahedron Letters, , vol. 30, # 20 p. 2707 - 2708
参考文献
Tetrahedron Letters, , vol. 30, # 20 p. 2707 - 2708
