(E)-beta-甲氧基-alpha-甲基苯乙烯合成路线 (共 7 条)
反应条件
1: 1-methoxy-allene in tetrahydrofuran
T=20°C; 12 h;
2: iodobenzene With tetrabutyl ammonium fluoride; tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran; chloroform
T=65°C; 24 h; Further stages. Title compound not separated from byproducts.;
参考文献
Hayashi, Naoki; Kusano, Kazunao; Sekizawa, Shingo; Shibata, Ikuya; Yasuda, Makoto; Baba, Akio
Chemical Communications, 2007 , # 46 p. 4913 - 4915
反应条件
bis-triphenylphosphine-palladium(II) chloride; sodium carbonate in tetrahydrofuran
T=60°C; 4 h;
参考文献
Occhiato, Ernesto G.; Prandi, Cristina; Ferrali, Alessandro; Guarna, Antonio; Deagostino, Annamaria; Venturello, Paolo
Journal of Organic Chemistry, 2002 , vol. 67, # 20 p. 7144 - 7146
反应条件
bis-triphenylphosphine-palladium(II) chloride; sodium carbonate in tetrahydrofuran
T=60°C; 4 h;
参考文献
Occhiato, Ernesto G.; Prandi, Cristina; Ferrali, Alessandro; Guarna, Antonio; Deagostino, Annamaria; Venturello, Paolo
Journal of Organic Chemistry, 2002 , vol. 67, # 20 p. 7144 - 7146
反应条件
potassium tert-butylate; sec.-butyllithium in tetrahydrofuran
1.) -95 deg C, 3 h, 2.) -50 deg C, 1 h;
参考文献
Deagostino, Annamaria; Mella, Mariella; Prandi, Cristina; Venturello, Paolo
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 21 p. 2757 - 2760
反应条件
1-MCM-41 zeolite in tetrachloromethane
2 h; Heating; Title compound not separated from byproducts;
参考文献
Climent; Corma; Iborra; Navarro; Primo
Journal of Catalysis, 1996 , vol. 161, # 2 art. no. 0241, p. 783 - 789
反应条件
T=60°C; Kinetics; Further Variations:Reagents;
参考文献
Gronheid; Lodder; Ochiai; Sueda; Okuyama
Journal of the American Chemical Society, 2001 , vol. 123, # 36 p. 8760 - 8765
反应条件
T=60°C; Product distributionKinetics; Further Variations:SolventsReagentsTemperaturesReaction partners;
参考文献
Gronheid; Lodder; Ochiai; Sueda; Okuyama
Journal of the American Chemical Society, 2001 , vol. 123, # 36 p. 8760 - 8765