[(.eta.5-C5Me5)IrCl(methylenebis(N-2-hydroxyethylimidazole-H))]Cl in H2O; propan-2-ol byproducts: (CH3)2CO; High Pressure; in a Hastelloy Autoclave Minireactor at 50 atm in a mixt. H2O-alc. (9:1,v/v); heating at 110 or 200°C for 16 h under stirring in the pre sence of Ir-catalyst; after equilibration to atm. pressure and cooling to room temp., the solvent was removed by evapn.; the residue was dissolved in D2O; the yield was detd. by (1)H NMR in D2O;
(2,6-bis(diisopropylphosphinomethyl)pyridine)iridium(III)trihydride in tetrahydrofuran; water Kinetics; High Pressure; mixt. of Ir complex and aq. soln. of KOH placed in stainless autoclave; pressurized by equimolar mixt. of CO2 and H2; heated to 200°C (oil bath); stirred for 2 h; not isolated; detd. by (1)H NMR spectra;
