4,4-二甲基-2-戊酮合成路线 (共 111 条)
反应条件
1: 63 percent / di-tert-butyl hyponitrite / benzene / 2 h / 60 °C 2: 92 percent / aq. TBAF / tetrahydrofuran / 1 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society - Perkin Transactions 1, , # 8 p. 769 - 775
反应条件
water T=25°C; ΔH=1642 cal/mol; Thermodynamic data;
参考文献
Journal of the American Chemical Society, , vol. 103, # 15 p. 4473 - 4478
反应条件
in benzene-d6 (inert atm. in a vac); at 25°C, < 5 min; not isolated; NMR;
参考文献
Organometallics, , vol. 10, p. 3344 - 3362
参考文献
Journal of the Chemical Society, , p. 1328,1329
反应条件
methanol; ammonium hydrogen carbonate
参考文献
Journal of the Chemical Society, , p. 2627,2630
参考文献
Journal of the Chemical Society, , p. 2627,2630
反应条件
potassium permanganate; acetone
参考文献
Journal of the Chemical Society, , p. 2627,2630
反应条件
potassium hydroxide; sulfuric acid; tetrabutylammomium bromide 1.) H2O, 80 deg C, 2 h, 2.) overnight; Yield given. Multistep reaction;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 34, # 10 p. 2151 - 2155
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 10 p. 2324 - 2328
反应条件
diethyl ether; copper(l) chloride
参考文献
Acta Chemica Scandinavica (1947-1973), , vol. 12, p. 2007,2009
Journal of Organic Chemistry, , vol. 22, p. 170,174
参考文献
Journal of the American Chemical Society, , vol. 68, p. 1653