3-(三甲基锡烷基)-吡啶合成路线 （共 36 条）
反应条件
in ammonia
NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of 10 equiv. of sodium to soln. of 5 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirring with irradiation for 60 min; quenching with methyl iodide, adn. of diethyl ether, evapn. of ammonia, treating with water, extn. (diethyl ether), washing with water and brine, drying over MgSO4, filtration, evapn., recrystn. (ethanol), NMR and MS;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
in ammonia
NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2.2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirring with irradiation for 30 min; quenching with methyl iodide, adn. of diethyl ether, evapn. of ammonia, treating with water, extn. (diethyl ether), washing with water and brine, drying over MgSO4, filtration, evapn., recrystn. (ethanol), NMR and MS;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
in ammonia
NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2.2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirring with irradiation for 20 min; quenching with methyl iodide, adn. of diethyl ether, evapn. of ammonia, treating with water, extn. (diethyl ether), washing with water and brine, drying over MgSO4, filtration, evapn., distd in vac., NMR and MS;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
in ammonia
byproducts: C5H4N(OPO(OC2H5)2); NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of sodium to soln. of 2.2 or 1 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirring with irradiation for 10 or 60 min; quenching with methyl iodide, adn. of diethyl ether, evapn. of ammonia, treating with water, extn. (diethyl ether), washing with water and brine, drying over MgSO4, filtration, evapn., chromy. (silica gel, hexane/ethyl acetate (6:4)), elem. anal.;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
C6H4(NO2)2 in ammonia
NH3 (liquid); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2.2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv. and p-dinitrobenzene, stirring for 60 min in dark;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
C6H4(NO2)2 in ammonia
byproducts: C5H4N(OPO(OCH2CH3)2); NH3 (liquid); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv. and p-dinitrobenzene, stirring for 30 min; quenching, GC/MS anal.;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
in ammonia
NH3 (liquid); Irradiation (UV/VIS); (inert atm.); addn. of sodium to soln. of 2.2 or 5 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirring with irradiation for 180 min; quenching with methyl iodide, adn. of diethyl ether, evapn. of ammonia, treating with water, extn. (diethyl ether), washing with water and brine, drying over MgSO4, filtration, evapn., distd in vac., NMR and MS;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
in ammonia
NH3 (liquid); (inert atm.); addn. of 4.4 equiv. of sodium to soln. of 2 equiv. of tin compd. in liquid ammonia, addn. of 1 equiv. of pyridine deriv., stirringfor 180 min in dark; quenching, GC/MS anal.;
参考文献
Silbestri, Gustavo F.; Lo Fiego, Marcos J.; Lockhart, Maria T.; Chopa, Alicia B.
Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2578 - 2585
反应条件
tetrabutyl-ammonium chloride; palladium diacetate in N,N-dimethyl-formamide
T=115 - 120°C; Stille reaction; 3 h;
参考文献
Somei, Masanori; Sayama, Shinsuke; Naka, Katsumi; Shinmoto, Kotaro; Yamada, Fumio
Heterocycles, 2007 , vol. 73, # C p. 537 - 554
反应条件
tetrabutyl-ammonium chloride; palladium diacetate
参考文献
Somei, Masanori; Sayama, Shinsuke; Naka, Katsumi; Yamada, Fumio
Heterocycles, 1988 , vol. 27, # 7 p. 1585 - 1588
