B-(1-甲基-1H-吲哚-4-基)-硼酸合成路线 (共 2 条)
反应条件
1: With n-butyllithium in tetrahydrofuran; pentane
T=-78°C; 1 h;
2: With tri-isopropoxy-borane in tetrahydrofuran; pentane
T=20°C; 4 h;
参考文献
Shoda, Motoshi; Kuriyama, Hiroshi
Patent: US2004/44258 A1, 2004 ;
Location in patent: Page 78 ;
反应条件
tetrahydroxydiboron; chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II); potassium acetate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in ethanol
T=80°C; 5 h; Inert atmosphere;
参考文献
Molander, Gary A.; Trice, Sarah L. J.; Kennedy, Steven M.; Dreher, Spencer D.; Tudge, Matthew T.
Journal of the American Chemical Society, 2012 , vol. 134, # 28 p. 11667 - 11673