(6CI,7CI)-2-对甲苯萘合成路线 （共 62 条）
反应条件
2Na(1+)*H2O*Cl4Pt(2-); tetrabutylammonium trifluoromethanesulphonate
T=100°C; 72 h;
参考文献
Wagner, Anna M.; Hickman, Amanda J.; Sanford, Melanie S.
Journal of the American Chemical Society, 2013 , vol. 135, # 42 p. 15710 - 15713
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tetrabutyl ammonium fluoride in tetrahydrofuran
T=35°C; 24 h; Inert atmosphere;
参考文献
Ding, Han; Chen, Yali; Cao, Weiguo; Wu, Kaicheng; Chen, Jie; Lee, Albert W. M.
Synthetic Communications, 2010 , vol. 40, # 7 p. 984 - 991
反应条件
in tetrahydrofuran
T=130°C; 36 h; Inert atmosphere;
参考文献
Minami, Hiroki; Wang, Xuan; Wang, Chao; Uchiyama, Masanobu
European Journal of Organic Chemistry, 2013 , # 35 p. 7891 - 7894
反应条件
palladium on activated charcoal
参考文献
Phillips; Chatterjee
Journal of the American Chemical Society, 1958 , vol. 80, p. 1360,1365
参考文献
Fuson; Berlin
Journal of the American Chemical Society, 1959 , vol. 81, p. 2130
反应条件
diethyl ether; benzene
Erhitzen des Reaktionsprodukts mit KHSO4 auf 170grad und Erhitzen des danach erhaltenen Reaktionsprodukts mit Palladium/Kohle auf 325grad;
参考文献
Fuson; Berlin
Journal of the American Chemical Society, 1959 , vol. 81, p. 2130
反应条件
1: 95 percent / various solvent(s) / 18 h / Heating
2: 21 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; dioxane / 48 h / Heating
View Scheme
参考文献
Brito, Cristela M.; Pinto, Diana C. G. A.; Silva, Artur M. S.; Silva, Ana M. G.; Tome, Augusto C.; Cavaleiro, Jose A. S.
European Journal of Organic Chemistry, 2006 , # 11 p. 2558 - 2569
反应条件
1: 95 percent / various solvent(s) / 18 h / Heating
2: 21 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; dioxane / 48 h / Heating
View Scheme
参考文献
Brito, Cristela M.; Pinto, Diana C. G. A.; Silva, Artur M. S.; Silva, Ana M. G.; Tome, Augusto C.; Cavaleiro, Jose A. S.
European Journal of Organic Chemistry, 2006 , # 11 p. 2558 - 2569
反应条件
1: β-naphthol With potassium phosphate; triethylamine; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate in 1,4-dioxane
T=100°C; 3 h; Inert atmosphere;
2: p-methylphenylboronic acid With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in 1,4-dioxane
T=100 - 110°C; Suzuki-Miyaura coupling; Inert atmosphere;
参考文献
Chen, Guo-Jun; Huang, Jie; Gao, Lian-Xun; Han, Fu-She
Chemistry - A European Journal, 2011 , vol. 17, # 14 p. 4038 - 4042
反应条件
1.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / |Inert atmosphere
1.2: -78 - 0 °C
2.1: tetrahydrofuran / 24 h / 110 °C / |Inert atmosphere
View Scheme
参考文献
Minami, Hiroki; Wang, Xuan; Wang, Chao; Uchiyama, Masanobu
European Journal of Organic Chemistry, 2013 , # 35 p. 7891 - 7894
