iso-propylmagnesium bromide; bis(cyclopentadienyl)titanium dichloride in diethyl ether T=20°C; 1 h; in dependence on solvent, reaction time, catalyst; Product distributionMechanism;
magnesium oxide; isopropyl alcohol T=199.85°C; reduction of the title compound and nonconjugated hex-5-en-2-one by 2-propanol over MgO; other temperatures; Product distribution;
参考文献
Polish Journal of Chemistry, , vol. 73, # 3 p. 561 - 563
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 29, # 4 p. 621 - 625
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 870 - 874