反应条件
1: sodium t-butanolate; palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether / tetrahydrofuran / 8 h / 58 - 64 °C / |Inert atmosphere
2: potassium tert-butylate; RuCl2[(S)-(DM-SEGPHOS)][(S)-DAIPEN]; hydrogen / isopropyl alcohol / 4 h / 20 - 25 °C / 4913.04 - 5171.62 Torr / |Inert atmosphere
View Scheme
参考文献
Chung, John Y. L.; Steinhuebel, Dietrich; Krska, Shane W.; Hartner, Fred W.; Cai, Chaoxian; Rosen, Jonathan; Mancheno, Danny E.; Pei, Tao; Dimichele, Lisa; Ball, Richard G.; Chen, Cheng-Yi; Tan, Lushi; Alorati, Antony D.; Brewer, Sarah E.; Scott, Jeremy P.
Organic Process Research and Development, 2012 , vol. 16, # 11 p. 1832 - 1845