2,7-二甲基-3,5-辛二炔-2,7-二醇合成路线 （共 40 条）
反应条件
copper acetylacetonate; iron (III) acetylacetonate; potassium carbonate in N,N-dimethyl-formamide
T=50°C; 24 h;
参考文献
Meng, Xu; Li, Chuanbin; Han, Baochun; Wang, Tiansheng; Chen, Baohua
Tetrahedron, 2010 , vol. 66, # 23 p. 4029 - 4031
反应条件
potassium iodide in N,N-dimethyl-formamide
T=120°C; 12 h;
参考文献
Chen, Zhengwang; Jiang, Huanfeng; Wang, Azhong; Yang, Shaorong
Journal of Organic Chemistry, 2010 , vol. 75, # 19 p. 6700 - 6703
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine; triphenylphosphine in toluene
T=85°C; Sonogashira cross-coupling; Inert atmosphere;
参考文献
Kane, Christopher M.; Meyers, Tiffany B.; Yu, Xin; Gerken, Michael; Etzkorn, Markus
European Journal of Organic Chemistry, 2011 , # 16 p. 2969 - 2980
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine in toluene
T=85°C; Sonogashira cross-coupling; Inert atmosphere;
参考文献
Kane, Christopher M.; Meyers, Tiffany B.; Yu, Xin; Gerken, Michael; Etzkorn, Markus
European Journal of Organic Chemistry, 2011 , # 16 p. 2969 - 2980
反应条件
hydroxylamine hydrochloride; ethylamine; copper(l) chloride in methanol; water
T=0°C; 0.166667 h;
参考文献
Weng, Yue; Cheng, Ben; He, Chuan; Lei, Aiwen
Angewandte Chemie - International Edition, 2012 , vol. 51, # 38 p. 9547 - 9551
参考文献
Chem.Werke Huels
Patent: DE885846 , 1942 ;
反应条件
pyridine; copper in benzene
12 h; Heating;
参考文献
Xue, Song; Meng, Ling-Guo; Guo, Qing-Xiang
Synthetic Communications, 2008 , vol. 38, # 13 p. 2243 - 2251
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran
T=25°C; Sonogashira coupling; 6 h;
参考文献
Gallagher, William P.; Maleczka Jr., Robert E.
Journal of Organic Chemistry, 2003 , vol. 68, # 17 p. 6775 - 6779
反应条件
triethylamine; copper(I) bromide; lithium bromide in tetrahydrofuran; dimethyl sulfoxide
T=95°C; Sonogashira Cross-Coupling; 13 h; Inert atmosphere; Reagent/catalystSolventTemperatureTimeConcentration;
参考文献
Parshina; Tantsyrev; Grishchenko; Trofimov
Russian Journal of Organic Chemistry, 2013 , vol. 49, # 3 p. 412 - 416
Zh. Org. Khim., 2013 , vol. 49, # 3 p. 425 - 428,4
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; triethylamine in acetone
T=20°C; 20 h;
参考文献
Zhang, Songlin; Liu, Xiaoyan; Wang, Tongqiang
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1463 - 1466
