4-三甲硅基-3-丁炔-2-酮合成路线 （共 32 条）
反应条件
water; pyridinium chlorochromate in dichloromethane 2 h; Ambient temperature;
参考文献
Chemische Berichte, , vol. 117, # 10 p. 3004 - 3020
反应条件
1.1: BuLi / tetrahydrofuran; hexane / -78 °C 1.2: 97 percent / tetrahydrofuran; hexane / 3 h / 0 °C 2.1: 21 percent / aluminum chloride / CH2Cl2 / -20 °C View Scheme
参考文献
Tetrahedron, , vol. 58, # 24 p. 4975 - 4980
反应条件
1: 81 percent / p-toluenesulfonic acid / benzene / Heating 2: 1.) BuLi / 1.) THF, -65 deg C, 30 min; 2.) THF, overnight, -65 deg C to 25 deg C 3: 63 percent / H2SO4 / acetone; H2O / 5 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 39, # 19 p. 3073 - 3082
反应条件
1: 1.) BuLi / 1.) THF, -65 deg C, 30 min; 2.) THF, overnight, -65 deg C to 25 deg C 2: 63 percent / H2SO4 / acetone; H2O / 5 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 39, # 19 p. 3073 - 3082
参考文献
Journal of Organometallic Chemistry, , vol. 625, # 2 p. 140 - 147
反应条件
lithium aluminium tetrahydride; Darvon-OH; tetrabutyl ammonium fluoride 2) THF; Multistep reaction. Title compound not separated from byproducts;
参考文献
Marshall, James A.; Wang, Xiao-jun
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1242 - 1252
参考文献
Shostakovskii,M.F. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1968 , vol. 38, p. 1172 - 1176,1126 - 1129
反应条件
lithium aluminium tetrahydride; Darvon-OH; tetrabutyl ammonium fluoride 2) THF; Multistep reaction. Title compound not separated from byproducts;
参考文献
Marshall, James A.; Wang, Xiao-jun
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1242 - 1252
反应条件
acetic acid in ethanol Heating;
参考文献
Cuadrado, Purificacion; Gonzalez-Nogal, Ana M; Valero, Raquel
Tetrahedron, 2002 , vol. 58, # 24 p. 4975 - 4980
反应条件
acetic acid in ethanol Heating;
参考文献
Cuadrado, Purificacion; Gonzalez-Nogal, Ana M; Valero, Raquel
Tetrahedron, 2002 , vol. 58, # 24 p. 4975 - 4980
